Chemical Compatibility and Performance Optimization in Natural Fiber-Based Polymer Composites


Authors : J. Sethubathi

Volume/Issue : Volume 10 - 2025, Issue 8 - August


Google Scholar : https://tinyurl.com/289unsr4

Scribd : https://tinyurl.com/5n886yye

DOI : https://doi.org/10.38124/ijisrt/25aug949

Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.

Note : Google Scholar may take 30 to 40 days to display the article.


Abstract : Natural fiber–reinforced polymer composites (NFPCs) are increasingly regarded as sustainable substitutes for conventional composites owing to their environmental merits, such as inherent biodegradability and comparatively low energy costs during manufacturing. Nonetheless, the intrinsic inadequacy of chemical bonding between the cellulosic fibers and the synthetic polymer matrices limits the realization of their anticipated end-use advantages. To circumvent this barrier and subsequently improve the composite’s mechanical, thermal, and environmental outcomes, selective chemical functionalization of the reinforcements has obtained renewed investigative momentum. This review systematically elaborates on the fundamental mechanisms governing fiber–polymer interlinking and consolidates recent advancements in tailored oxidative, esterification, and silane modification procedures directed toward maximum fibre–matrix matching. A comprehensive quantitative and qualitative assessment of how these interface-engineering strategies modulate composite performance is presented, thereby directing the selection and refinement of treatments toward optimized exploitation across heterogeneous industrial environments ranging from transportation to civil infrastructure.

Keywords : Chemical Compatibility, Performance Optimization, Natural Fiber Composites, Polymer Matrix, Interfacial Bonding, Fiber Modification, Mechanical Properties, Thermal Properties, Biodegradable Polymers, Sustainable Materials, Composite Materials, Material Science, Polymer Science.

References :

  1. J. G. Murali, S. Marimuthu, P. Vignesh, P. Prakash, G. V. Kaliyannan, and S. Karthikeyan, "Influences of silicon carbide particles on tensile performance and hardness behavior of polyethylene composites made via injection mold," in AIP Conference Proceedings, 2025, p. 020292.
  2. K. Arunraja, P. Muthugounder, S. Karthikeyan, S. Ganesan, A. Gowrishankar, and B. Muruganandhan, "Influences of jute fiber and alumina nanoparticles on behaviour of polyester composite synthesized via hand layup route," in AIP Conference Proceedings, 2025, p. 020290.
  3. S. Ganesan, G. Boopathi, S. Kalaiarasan, B. E. Jebasingh, P. Muruganandhan, and S. Karthikeyan, "Synthesis and characteristics evaluation of epoxy hybrid nanocomposite featured with ramie fiber and SiC," in AIP Conference Proceedings, 2025, p. 020241.
  4. S. Sundaram and M. Kumarasamy, "Joint characteristics and process parameters optimization on friction stir welding of AA 2024-T6 and AA 5083-H111 aluminium alloys," Journal of the Serbian Chemical Society, vol. 89, pp. 1387-1399, 2024.
  5. E. M. Sundaram, V. Santhosh, M. Sundaresan, and S. Sakthivel, "Machine Learning Model for Predicting Tensile Strength of Aluminium Alloy 5083," in 2025 International Conference on Advanced Computing Technologies (ICoACT), 2025, pp. 1-6.
  6. G. Kaliyaperumal, N. Karthikeyan, C. Priya, S. Karthikeyan, M. Ammaiappan, and S. Prabagaran, "Hybrid reinforcement’s actions on flexural/tensile/impact strength of polyester composite made via injection molding route," in AIP Conference Proceedings, 2025.
  7. S. Karthikeyan, S. Ganesan, A. Suresh, P. Muruganandhan, B. E. Jebasingh, and K. Manogar, "Impact of E glass fiber on functional properties of low density polyethyle composite made via compression mold," in AIP Conference Proceedings, 2025, p. 020243.
  8. S. Karthikeyan, A. Jagadheeswari, J. G. Murali, G. Kaliannan, S. Marimuthu, and S. Kalaiarasan, "Hot compression actions on functional behavior of polyester composite configured with basalt fiber," in AIP Conference Proceedings, 2025, p. 020294.
  9. S. Karthikeyan, M. Karthick, M. Munipalli, N. Sankar, L. Suriyaprakash, and P. Muthugounder, "Effect of roselle fiber on physical and thermal behaviour of polypropylene nanocomposite developed by conventional route," in AIP Conference Proceedings, 2025, p. 020223.
  10. V. Geethalakshmi, N. Nalini, and C. Theivarasu, "Anticancer activity of morpholine schiff base complexes," in AIP Conference Proceedings, 2020, p. 100016.
  11. N. Nalini, K. S. Thangamani, V. Geethalakshmi, and S. Nithyashree, "14 - Innovative nanosensors for detection of dyes," in Nanotechnology-based Sensors for Detection of Environmental Pollution, F. M. Policarpo Tonelli, A. Roy, M. Ozturk, and H. C. A. Murthy, Eds., ed: Elsevier, 2024, pp. 265-275.
  12. R. Janani, S. Bhuvana, V. Geethalakshmi, R. Jeyachitra, K. Sathishkumar, R. Balu, et al., "Micro and nano plastics in food: A review on the strategies for identification, isolation, and mitigation through photocatalysis, and health risk assessment," Environmental Research, vol. 241, p. 117666, 2024.
  13. V. Geethalaksmi and C. Theivarasu, "Synthesis and Characterization of Samarium (III (and Gadolinium (III) Complexes Containing2-Methoxy-6-((2-(Piperazin-1yl) Ethylimino) Methyl) Phenol as Ligand," International Journal of ChemTech Research, vol. 9, pp. 941-949, 2016.
  14. V. Geethalakshmi, C. Theivarasu, N. Nalini, and V. Gomathi, "Spectroscopic, microbial studies and in-vitro anticancer activity of Pyridine Schiff base ligand and its lanthanum complexes," Bulletin of Materials Science, vol. 46, p. 223, 2023.
  15. P. Kumaravel, P. Suresh, K. V. Raja, and T. Sekar, "Improvement of micro-electrochemical discharge machining of austenitic stainless steel 316L using NaOH electrolyte containing N2," International Journal of Electrochemical Science, vol. 17, p. 220747, 2022.
  16. M. Kumar, S. Ragunathan, P. S. Velu, M. Suresh, V. Srinivashan, and P. Kumaravel, "Effect of zinc nickel coating on properties of Nitrided AISI 1040 steel," Materials Research Express, vol. 6, p. 086547, 2019.
  17. S. Karthikeyan, A. Karthikeyan, B. K. Jose, S. Marimuthu, T. Sathish, and J. G. Murali, "Influences of titanium carbide on behaviour of jute fiber made epoxy composite for automotive usage," in AIP Conference Proceedings, 2025, p. 020296.
  18. S. Karthikeyan, S. Manivannan, R. Venkatesh, S. Karthikeyan, R. Anand, and S. Sasikaran, "Optimization and Characteristics of Multimodal Binder on Polymer Nanocomposite for Lightweight Applications," Journal of Environmental Nanotechnology, vol. 13, pp. 207-216, 2024.
  19. K. Krishnasamy, J. Palanisamy, and M. Bhuvaneshwarana, "A review on natural fiber reinforced biocomposites properties and its applications," in AIP Conference Proceedings, 2024, p. 020015.
  20. B. L. Simon, K. Paramasivam, S. Manickam, and S. Madesh, "Performance investigation of electrochemical micro machining process using salt free composite electrolytes," Russian Journal of Applied Chemistry, vol. 97, pp. 463-475, 2024.
  21. S. Hemalatha, S. Shalini, U. Sathya, P. Kumaravel, S. V. Krishna, and P. H. KULKARNI, "AI BASED CLUSTER HEAD BASED MOBILE ADHOC NETWORK FOR PERFORMANCE IMPROVEMENT," Journal of Theoretical and Applied Information Technology, vol. 102, pp. 8818-8826, 2024.
  22. P. Kumaravel, K. V. Raja, and P. Suresh, "Mechanical behavior of LM26/SiC/TiO2/Ni-Gr reinforced hybrid metal matrix composites–An experimental investigation," Journal of Ceramic Processing Research, vol. 24, pp. 569-577, 2023.
  23. R. Venkatesh, G. Kaliyaperumal, S. Manivannan, S. Karthikeyan, V. Mohanavel, M. E. M. Soudagar, et al., "Characteristics of Magnesium Composite Reinforced with Silicon Carbide and Boron Nitride via Liquid Stir Processing," SAE Technical Paper 0148-7191, 2024.
  24. R. Venkatesh, N. Aravindan, S. Manivannan, S. Karthikeyan, V. Mohanavel, M. E. M. Soudagar, et al., "Study of Natural Fiber Incorporated Polypropylene Composite Laminate for Lightweight Applications," SAE Technical Paper 0148-7191, 2024.
  25. R. Venkatesh, G. Kaliyaperumal, S. Manivannan, S. Karthikeyan, N. Aravindan, V. Mohanavel, et al., "Effect of Silicon Carbide Addition and Jute Fiber Surface Treatment on Functional Qualities of Low-Density Polyethylene Composites," SAE Technical Papers, 2024.
  26. R. Venkatesh, G. Kaliyaperumal, S. Manivannan, S. Karthikeyan, V. Mohanavel, M. E. M. Soudagar, et al., "Performance Evaluation of Nano Silicon Carbide Configured Aluminium Alloy with Titanium Nanocomposite via Semisolid Stir Cast," SAE Technical Paper 0148-7191, 2024.
  27. S. Karthikeyan, S. Manivannan, R. Venkatesh, S. Karthikeyan, A. Kuila, and S. Lakshmanan, "Impact of Binder Selection on Functional Properties of Polymer Nanocomposite Featured with Metal Oxide Nanoparticle," Journal of Environmental Nanotechnology, vol. 13, pp. 262-270, 2024.
  28. S. Manivannan, R. Venkatesh, G. Kaliyaperumal, S. Karthikeyan, V. Mohanavel, M. E. M. Soudagar, et al., "Magnesium Alloy Hybrid Composite Properties are Featured with Boron Carbide Particle for Automotive Seat Frame Usage," SAE Technical Paper 0148-7191, 2024.
  29. S. Marimuthu, R. Ashokkumar, S. Karthick, A. Karthikeyan, S. Karthikeyan, and R. Gunasekaran, "Synthetic fiber featured epoxy composite for light weight application: Performance measures," in AIP Conference Proceedings, 2025, p. 020293.
  30. P. Muthugounder, R. D. Kumar, S. Ganesan, A. Gowrishankar, S. Karthikeyan, and B. E. Jebasingh, "Featuring of boron nitride on high density polyethylene/sisal fiber composite: Characteristics evaluation," in AIP Conference Proceedings, 2025, p. 020246.
  31. S. Raja, R. Ali, S. Karthikeyan, R. Surakasi, R. Anand, N. Devarasu, et al., "Energy-Efficient FDM Printing of Sustainable Polymers: Optimization Strategies for Material and Process Performance," Applied Chemical Engineering, vol. 7, p. 10.59429, 2024.
  32. S. Raja, R. M. Ali, Y. V. Babar, R. Surakasi, S. Karthikeyan, B. Panneerselvam, et al., "Integration of nanomaterials in FDM for enhanced surface properties: Optimized manufacturing approaches," Applied Chemical Engineering, vol. 7, 2024.
  33. S. Raja, M. A. Rusho, K. C. Sekhar, K. S. Kumar, K. Alagarraja, A. P. Kumar, et al., "Innovative surface engineering of sustainable polymers: Toward green and high-performance materials," Applied Chemical Engineering, vol. 7, 2024.
  34. A. Saravanakumar, J. G. Murali, A. Kuila, S. Karthikeyan, S. Ganesan, and A. Gowrishankar, "Biodegradable bast fiber made polypropylene composite via hot compression: Characteristics study," in AIP Conference Proceedings, 2025, p. 020291.
  35. N. Saravanan, S. Karthikeyan, S. Marimuthu, J. G. Murali, M. Prasath, and A. Gowrishankar, "Effect of surface treatment on characteristics of bast fiber incorporated polyethylene composite: Behavior study," in AIP Conference Proceedings, 2025, p. 020295.
  36. R. Subramani, R. M. Ali, R. Surakasi, D. R. Sudha, S. Karthick, S. Karthikeyan, et al., "Surface metamorphosis techniques for sustainable polymers: Optimizing material performance and environmental impact," Applied Chemical Engineering, vol. 7, pp. 11-11, 2024.

Natural fiber–reinforced polymer composites (NFPCs) are increasingly regarded as sustainable substitutes for conventional composites owing to their environmental merits, such as inherent biodegradability and comparatively low energy costs during manufacturing. Nonetheless, the intrinsic inadequacy of chemical bonding between the cellulosic fibers and the synthetic polymer matrices limits the realization of their anticipated end-use advantages. To circumvent this barrier and subsequently improve the composite’s mechanical, thermal, and environmental outcomes, selective chemical functionalization of the reinforcements has obtained renewed investigative momentum. This review systematically elaborates on the fundamental mechanisms governing fiber–polymer interlinking and consolidates recent advancements in tailored oxidative, esterification, and silane modification procedures directed toward maximum fibre–matrix matching. A comprehensive quantitative and qualitative assessment of how these interface-engineering strategies modulate composite performance is presented, thereby directing the selection and refinement of treatments toward optimized exploitation across heterogeneous industrial environments ranging from transportation to civil infrastructure.

Keywords : Chemical Compatibility, Performance Optimization, Natural Fiber Composites, Polymer Matrix, Interfacial Bonding, Fiber Modification, Mechanical Properties, Thermal Properties, Biodegradable Polymers, Sustainable Materials, Composite Materials, Material Science, Polymer Science.

CALL FOR PAPERS


Paper Submission Last Date
30 - November - 2025

Video Explanation for Published paper

Never miss an update from Papermashup

Get notified about the latest tutorials and downloads.

Subscribe by Email

Get alerts directly into your inbox after each post and stay updated.
Subscribe
OR

Subscribe by RSS

Add our RSS to your feedreader to get regular updates from us.
Subscribe