Experimental Analysis & Study of Intumescent Flame Retardant Coating for Polymeric Material Using LOI & Cone Calorimetry


Authors : Suresh Lade; Sonu Kumar; Parmar Surajkumar; Shubham Kumar Jha; Manjit Kumar; Shivangi Sonowal

Volume/Issue : Volume 11 - 2026, Issue 1 - January


Google Scholar : https://tinyurl.com/9adyu5jc

Scribd : https://tinyurl.com/537u2b56

DOI : https://doi.org/10.38124/ijisrt/26jan1228

Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.


Abstract : The fire behavior of polymeric materials remains a critical concern in applications requiring enhanced safety against ignition and fire growth. Polyvinyl chloride (PVC), despite its widespread use, exhibits unfavorable fire characteristics under sustained heat exposure. This research paper presents an experimental evaluation of a surface- applied flame-retardant coating on PVC, with particular focus on the influence of coating thickness on fire performance. A comparative analysis between uncoated and coated PVC samples is conducted using cone calorimeter testing and Limiting Oxygen Index (LOI) measurements. Key fire parameters related to ignition resistance, heat release, and combustion stability are examined to assess the effectiveness of the coating. The results demonstrate a clear improvement in fire performance for coated specimens, including delayed ignition and reduced heat release. However, the enhancement does not increase proportionally with coating thickness, indicating diminishing returns beyond an optimal thickness. The findings emphasize the importance of thickness optimization in flame-retardant coatings and provide practical insight for improving passive fire protection strategies for polymeric materials in fire-sensitive applications.

Keywords : Polyvinyl Chloride (PVC); Flame-Retardant Coating; Coating Thickness; Cone Calorimeter; Limiting Oxygen Index; Fire Performance.

References :

  1. Alongi, J., et al. (2013). Recent advances in flame retardant materials for textiles and polymers. Materials, 6(10),45564583.
  2. Jimenez, M., Duquesne, S., & Bourbigot, S. (2006). Intumescent fire protective coatings: Toward a better understanding of their mechanism of action. Progress in Organic Coatings, 55(4), 298-306.
  3. Horrocks, A. R., & Price, D. (2008). Fire Retardant Materials. CRC Press.
  4. Gu, J., Zhang, G., Dong, S., et al. (2007). Study on preparation and fire-retardant mechanism analysis of intumescent flame-retardant coatings. Surface & Coatings Technology, 201 (9-11),7835-7841.
  5. Weil, E. D., & Levchik, S. V. (2009). Flame retardants for plastics and textiles:Practical applications. Carl Hanser Verlag GmbH & Co.
  6. Suraj et al. (2024). Ion exchange resin and boric acid synergy in MAP-based IFR systems. Advanced Polymer Research.
  7. Suraj et al. (2024). Effect of xylene, paraffin, and resin additives on IFR coating properties. Internal Technical Report.
  8. Kandola, B. K., & Horrocks, A. R. (1996). Char formation in flame-retardant polymer systems. Fire and Materials, 20(5),191-197.
  9. ASTM D2863-19. Standard Test Method for Measuring the Minimum Oxygen Concentration to Support Candle-Like Combustion of Plastics (Oxygen Index). ASTM International.
  10. TD2863-19. Internal SOP Document, Department of Chemical Engineering.
  11. Shen L. et al., “Flame-retardant mechanisms & preparation of polymeric materials,” Polymers, 2021.
  12. Jin, X. B., Jiang, Z. H., Wen, X. W., Zhang, R., and Qin, D. C. (2017). "Flame retardant properties of laminated bamboo lumber treated with monoammonium phosphate (MAP) and boric acid/borax (SBX) compounds," BioRes. 12(3)
  13. Functionalizing Ammonium Polyphosphate with BoronBased Compounds to Improve the Flame Retardancy and Anti-Dripping of Polylactic Acid Resin Sheng-chao Huang, Xiaosui Chen, Yipei Zhang, Yuhang Huang, Shuzheng Liu
  14. ISO 4589-2:2017 Plastics - Determination of burning behaviour by oxygen index -Part 2:Ambient-temperature test
  15. Calcium Carbonate as Functional Filler in Polyamide 12Manipulation of the Thermal and Mechanical Properties by Fabio Ippolito. 1,Gunter Hübner 2,Tim Claypole and Patrick Gane

The fire behavior of polymeric materials remains a critical concern in applications requiring enhanced safety against ignition and fire growth. Polyvinyl chloride (PVC), despite its widespread use, exhibits unfavorable fire characteristics under sustained heat exposure. This research paper presents an experimental evaluation of a surface- applied flame-retardant coating on PVC, with particular focus on the influence of coating thickness on fire performance. A comparative analysis between uncoated and coated PVC samples is conducted using cone calorimeter testing and Limiting Oxygen Index (LOI) measurements. Key fire parameters related to ignition resistance, heat release, and combustion stability are examined to assess the effectiveness of the coating. The results demonstrate a clear improvement in fire performance for coated specimens, including delayed ignition and reduced heat release. However, the enhancement does not increase proportionally with coating thickness, indicating diminishing returns beyond an optimal thickness. The findings emphasize the importance of thickness optimization in flame-retardant coatings and provide practical insight for improving passive fire protection strategies for polymeric materials in fire-sensitive applications.

Keywords : Polyvinyl Chloride (PVC); Flame-Retardant Coating; Coating Thickness; Cone Calorimeter; Limiting Oxygen Index; Fire Performance.

Paper Submission Last Date
28 - February - 2026

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