Flotation Tests of Poor Copper and Cobalt Tailings from Dike 3 of Kipushi


Authors : Mungwa Kalundu Gaylord; Ipang Ruwej Rebecca; Ndala Mbavu Bavon; Zeka Mujinga

Volume/Issue : Volume 10 - 2025, Issue 10 - October


Google Scholar : https://tinyurl.com/2tdzc5zk

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DOI : https://doi.org/10.38124/ijisrt/25oct823

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Abstract : Current technological developments are pushing companies to recover waste and recycle refuse. With this in mind, the treatment of waste from dam 3 represents a significant opportunity to recover the metals contained in this waste and thus maximise the use of these resources.This recovery is achieved by increasing the content of recoverable metals in the tailings, based on a characterisation of our sample, which leads us to choose a concentration technique that is slightly more suitable for this type of tailings. Having chosen froth flotation as the technique, the first part of the experiment focused on characterising the sample through mineralogical analysis, chemical analysis and granulochemical analysis. The results showed that total copper is at 0.94% and oxide at 0.85%. The main mineral is malachite, with traces of chrysocolla. The gangue consists of quartz, iron oxides, pyrite and dolomite; it is therefore dolomitic in terms of the Cutotal/CaOsoluble ratio.The reject is crushed to a D70 of 75 microns in 20 minutes. The second part focused on laboratory flotation tests, with reagent doses such as NaHS and KAX maintained at 3000 g/t and 300 g/t for a recovery yield of 44.8% with a concentrate of 1.11%.We realised that the sulphide portion could be minimised to perform mixed flotation, so we moved on to oxide flotation by sulphurisation, where we varied the doses of all our reagents and obtained the following best doses.  NaHS and KAX: 500g/t and 50g/t, with an estimated content of 1.12%;  mixture: 200g/t, with a rough grade of 1.27%;  silicate: 100g/t, with a rough grade of 1.17%. These results simply show that the initial goal could not be achieved, but with this we can try to feed the leaching reject.

Keywords : Tailings Valorization, Oxide Flotation, Sulfidization, Malachite, Chrysocolla, Mine Waste Treatment, Copper Recovery, Flotation Reagents, Nahs, KAX, Leaching, Dam 3 Tailings, Ore Beneficiation, Dolomite, Dolomitic Gangue.

References :

  1. Blazy, P., & El-Aid, J. (2000a). Flottation : Aspects pratiques. Techniques d’ingénieur, Procédés Chimie Agro Bio, Procédés unitaires, j3360.
  2. Blazy, P., & El-Aid, J. (2000b). Flottation : Mécanismes et réactifs. Techniques d’ingénieur, Procédés Chimie Agro Bio, Procédés unitaires, j3350.
  3. Kitobo Samsoni, W. (2009). Dépollution et valorisation des rejets miniers sulfurés du Katanga : Cas des tailings de l’Ancien Concentrateur de Kipushi (Thèse de doctorat, Université de Liège, Belgique).
  4. Kongolo, M. (1991). Interaction de l’amaylxanthate de potassium avec la galène et la pyrite finement broyées : Conséquences sur la flottation (Thèse de doctorat, Institut National Polytechnique de Lorraine, Vandœuvre-lès-Nancy, France).
  5. Wills, B. A., & Napier-Munn, T. (2006). Mineral processing technology: An introduction to the practical aspects of ore treatment and mineral recovery (7e éd.). Elsevier Science & Technology Books.
  6. Abette, & Khitine. (1970). Manuel de minéralurgie descriptive. Éditions Mir, Moscou.
  7. Corneille, E. K., & Masson, A. (1973). Cours de minéralurgie et préparation des minerais. Éditions Derroux, Liège.
  8. Blazy, P. (1970). La valorisation des minerais. Presse Universitaire de France, Paris.
  9. Rickard, T. A. (2001). Concentration by flotation. New York.
  10. Nouioua, A. (2018). Lixiviation et extraction du fer à partir de la roche ferrique de la mine de l’Ouenza.
  11. Mbweb, P. (2017). Étude de la lixiviation en tas du minerai cupro-cobaltifère dans les mines de la province du Katanga en RDC.

Current technological developments are pushing companies to recover waste and recycle refuse. With this in mind, the treatment of waste from dam 3 represents a significant opportunity to recover the metals contained in this waste and thus maximise the use of these resources.This recovery is achieved by increasing the content of recoverable metals in the tailings, based on a characterisation of our sample, which leads us to choose a concentration technique that is slightly more suitable for this type of tailings. Having chosen froth flotation as the technique, the first part of the experiment focused on characterising the sample through mineralogical analysis, chemical analysis and granulochemical analysis. The results showed that total copper is at 0.94% and oxide at 0.85%. The main mineral is malachite, with traces of chrysocolla. The gangue consists of quartz, iron oxides, pyrite and dolomite; it is therefore dolomitic in terms of the Cutotal/CaOsoluble ratio.The reject is crushed to a D70 of 75 microns in 20 minutes. The second part focused on laboratory flotation tests, with reagent doses such as NaHS and KAX maintained at 3000 g/t and 300 g/t for a recovery yield of 44.8% with a concentrate of 1.11%.We realised that the sulphide portion could be minimised to perform mixed flotation, so we moved on to oxide flotation by sulphurisation, where we varied the doses of all our reagents and obtained the following best doses.  NaHS and KAX: 500g/t and 50g/t, with an estimated content of 1.12%;  mixture: 200g/t, with a rough grade of 1.27%;  silicate: 100g/t, with a rough grade of 1.17%. These results simply show that the initial goal could not be achieved, but with this we can try to feed the leaching reject.

Keywords : Tailings Valorization, Oxide Flotation, Sulfidization, Malachite, Chrysocolla, Mine Waste Treatment, Copper Recovery, Flotation Reagents, Nahs, KAX, Leaching, Dam 3 Tailings, Ore Beneficiation, Dolomite, Dolomitic Gangue.

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Paper Submission Last Date
31 - December - 2025

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