Authors :
Madhukeswara R. S.
Volume/Issue :
Volume 11 - 2026, Issue 6 - June
Google Scholar :
https://tinyurl.com/narrycba
Scribd :
https://tinyurl.com/5n8behhz
DOI :
https://doi.org/10.38124/ijisrt/26jun530
Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.
Abstract :
The effect of air annealing on the optical characteristics of CuO thin films produced on glass substrates by
Chemical Bath Deposition (CBD) process was studied by annealing the films in ambient air at different temperatures. The
films as deposited were air annealed at temperatures of 350°C and 450°C for one hour. Optical properties of the films were
studied by UV-Visible spectroscopy in the wavelength range of 200-1200 nm.
The results showed that the air annealing has a substantial effect on the optical behaviour of CuO thin films. As the
annealing temperature increased, significant changes in the absorbance and transmittance spectra were observed, indicating
an enhancement in the film quality and crystallinity. The absorption coefficient was observed to increase with annealing
temperature due to increased grain development and decreased flaw density. The optical band gap was calculated using the
Tauc’s relation. The band gap energy was gradually changed with increasing annealing temperature. These modifications
can be explained by structural reorganization, decrease of lattice defects and enhanced stoichiometry of CuO films during
the annealing.
This work shows that air annealing is a promising post-deposition procedure for tuning the optical characteristics of
CBD produced CuO thin films for their application in photovoltaic devices, photodetector and optoelectronic systems. The
results provide useful information on how to optimize the annealing conditions for obtaining better optical performance in
CuO-based thin-film devices.
Keywords :
CuO Thin Films, Chemical Bath Deposition, Air Annealing, Optical Properties, Optical Band Gap
References :
- Baranov, O., Bazaka, K., Belmonte, T., Riccardi, C., Roman, H. E., Mohandas, M.,..& Levchenko, I. (2023). Recent innovations in the technology and applications of low-dimensional CuO nanostructures for sensing, energy and catalysis. Nanoscale Horizons, 8(5), 568–602.
- Faisal, A. D., Aljubouri, A. A., & Khalef, W. K. (2026). Photodetector fabrication based on heterojunction of CuO/In₂O₃/Si nanostructures. Plasmonics, 21(2), 1831–1844.
- Steinhauer, S., Brunet, E., Maier, T., Mutinati, G. C., Köck, A., Freudenberg, O., ... & Resel, R. (2013). Gas sensing properties of novel CuO nanowire devices. Sensors and Actuators B: Chemical, 187, 50–57.
- Arya, S., Prerna, Singh, A., & Kour, R. (2019). Comparative study of CuO, CuO@Ag and CuO@Ag:La nanoparticles for their photosensing properties. Materials Research Express, 6(11), Article 116313.
- Ghule, B. G., & Mane, R. S. (2023). Chemical bath deposition for metal oxide nanostructures. In Solution Methods for Metal Oxide Nanostructures (pp. 267–292). Elsevier.
- Kadhim, K. R., & Mohammed, R. Y. (2022). Effect of annealing time on structure, morphology, and optical properties of nanostructured CdO thin films prepared by CBD technique. Crystals, 12(9), Article 1315.
- Sultana, J., Paul, S., Karmakar, A., Dalapati, G. K., & Chattopadhyay, S. (2018). Optimizing the thermal annealing temperature: Technological route for tuning the photo-detecting property of p-CuO thin films grown by chemical bath deposition method. Journal of Materials Science: Materials in Electronics, 29(15), 12878–12887.
- Abdel Rafea, M., & Roushdy, N. (2009). Determination of the optical band gap for amorphous and nanocrystalline copper oxide thin films prepared by SILAR technique. Journal of Physics D: Applied Physics, 42(1), Article 015413.
- Koshy, J., & George, K. C. (2015). Annealing effects on crystallite size and band gap of CuO nanoparticles. Catalysis, 5, 11.
- Sivaprakasam, S., Bharatan, S., Mohanam, R., & Subramaniyam, S. (2026). Effects of annealing on the radio frequency sputtered CuO/ZnO thin film heterostructure for optoelectronic applications. Materials, 19(4), Article 789.
The effect of air annealing on the optical characteristics of CuO thin films produced on glass substrates by
Chemical Bath Deposition (CBD) process was studied by annealing the films in ambient air at different temperatures. The
films as deposited were air annealed at temperatures of 350°C and 450°C for one hour. Optical properties of the films were
studied by UV-Visible spectroscopy in the wavelength range of 200-1200 nm.
The results showed that the air annealing has a substantial effect on the optical behaviour of CuO thin films. As the
annealing temperature increased, significant changes in the absorbance and transmittance spectra were observed, indicating
an enhancement in the film quality and crystallinity. The absorption coefficient was observed to increase with annealing
temperature due to increased grain development and decreased flaw density. The optical band gap was calculated using the
Tauc’s relation. The band gap energy was gradually changed with increasing annealing temperature. These modifications
can be explained by structural reorganization, decrease of lattice defects and enhanced stoichiometry of CuO films during
the annealing.
This work shows that air annealing is a promising post-deposition procedure for tuning the optical characteristics of
CBD produced CuO thin films for their application in photovoltaic devices, photodetector and optoelectronic systems. The
results provide useful information on how to optimize the annealing conditions for obtaining better optical performance in
CuO-based thin-film devices.
Keywords :
CuO Thin Films, Chemical Bath Deposition, Air Annealing, Optical Properties, Optical Band Gap