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Innovations in Energy Storage: The Role of 2D Halide Perovskites in Supercapacitors


Authors : Sonu

Volume/Issue : Volume 11 - 2026, Issue 4 - April


Google Scholar : https://tinyurl.com/ye7ktvhd

Scribd : https://tinyurl.com/5xn86fth

DOI : https://doi.org/10.38124/ijisrt/26apr1278

Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.


Abstract : Supercapacitors and other energy storage devices have garnered a lot of attention due to their beneficial uses. In this sense, Halide perovskites (HPs) in two dimensions (2D) are attractive but relatively unexplored capacitor materials. 2D HPs have excellent properties such as superior electronic and ionic conductivity and also better stability compared to their 3D counterpart. 1,2 Improved stability originates from the incorporation of hydrophobic large organic amine into the perovskite structure. In our work, we have synthesized and studied 2D HPs to understand the super capacitive nature in presence and absence of light. We have synthesized and characterized our investigated materials by using FESEM, XRD, etc. Synthesized HPs have shown improved capacitive behavior and capacitance results and good operational stability owing to its slower ion kinetics. We fabricated electrodes by using a slurry through mixing of the active materials (perovskites) (70%), activated carbon (15%), and PVDF (15%) as a binder. onto a graphite sheet, followed by over-night drying at ∼70 °C under vacuum. Super capacitive behavior has been measured using electrochemical characterizations techniques such as galvanostatic charge discharge and cyclic voltammetry methods. The achieved specific capacitance values are 41 F/g, 18 F/g and 7.8 F/g at 0.1, 0.2 and 0.5 A/g current density, respectively. Preliminary research findings show promising results and good operational stability for 2D HPs based electrochemical supercapacitors. The operational stability can be attributed to the incorporation of hydrophobic organic ligands. Our work thus highlights the potential of unexplored 2D HPs as a futuristics supercapacitor material.

Keywords : Hybrid Halide Perovskites, Two-Dimensional, Energy Storage, Electrochemical Supercapacitors, Photo-Rechargeable.

References :

  1. Sandhu, A., & Chini, M. K. (2024). 2D and 3D Halide Perovskite‐Based Supercapacitors. ChemistrySelect9(12), e202304441.
  2. Kumar, Ramesh, et al. "Photorechargeable hybrid halide perovskite supercapacitors." ACS Applied Materials & Interfaces 14.31 (2022): 35592-35599.
  3. Sharma, K., Arora, A., & Tripathi, S. K. (2019). Review of supercapacitors: Materials and devices. Journal of Energy Storage21, 801-825.
  4. Jeong, J., Kim, M., Seo, J., Lu, H., Ahlawat, P., Mishra, A., ... & Kim, J. Y. (2021). Pseudo-halide anion engineering for α-FAPbI3 perovskite solar cells. Nature592(7854), 381-385.
  5. Tsai, H., Nie, W., Cheruku, P., Mack, N. H., Xu, P., Gupta, G., ... & Wang, H. L. (2015). Optimizing composition and morphology for large-grain perovskite solar cells via chemical control. Chemistry of Materials27(16), 5570-5576.
  6. Kumar, R., Kumar, J., Srivastava, P., Moghe, D., Kabra, D., & Bag, M. (2020). Unveiling the morphology effect on the negative capacitance and large ideality factor in perovskite light-emitting diodes. ACS applied materials & interfaces12(30), 34265-34273.
  7. Johnston, M. B., & Herz, L. M. (2016). Hybrid perovskites for photovoltaics: charge-carrier recombination, diffusion, and radiative efficiencies. Accounts of chemical research49(1), 146-154.
  8. Sun, Y., Peng, J., Chen, Y., Yao, Y., & Liang, Z. (2017). Triple-cation mixed-halide perovskites: towards efficient, annealing-free and air-stable solar cells enabled by Pb (SCN) 2 additive. Scientific reports7(1), 46193..
  9. Srivastava, P., Kumar, R., & Bag, M. (2020). Discerning the role of an A-site cation and X-site anion for ion conductivity tuning in hybrid perovskites by photoelectrochemical impedance spectroscopy. The Journal of Physical Chemistry C125(1), 211-222.
  10. Wu, K. J., Young, W. B., & Young, C. (2023). Structural supercapacitors: A mini-review of their fabrication, mechanical & electrochemical properties. Journal of Energy Storage72, 108358.
  11. Ahmad, F., Zahid, M., Jamil, H., Khan, M. A., Atiq, S., Bibi, M., ... & Samreen, A. (2023). Advances in graphene-based electrode materials for high-performance supercapacitors: a review. Journal of Energy Storage72, 108731.
  12. Sahu, R. K., Gangil, S., Bhargav, V. K., Sahu, P., & Ghritalahre, B. (2023). Synthesizing biomass into nano carbon for use in high-performance supercapacitors-a brief critical review. Journal of Energy Storage72, 108348.
  13. Chini, M. K., & Chatterjee, S. (2017). Hydrothermally reduced nano porous graphene–polyaniline nanofiber composites for supercapacitor. FlatChem1, 1-5.

Supercapacitors and other energy storage devices have garnered a lot of attention due to their beneficial uses. In this sense, Halide perovskites (HPs) in two dimensions (2D) are attractive but relatively unexplored capacitor materials. 2D HPs have excellent properties such as superior electronic and ionic conductivity and also better stability compared to their 3D counterpart. 1,2 Improved stability originates from the incorporation of hydrophobic large organic amine into the perovskite structure. In our work, we have synthesized and studied 2D HPs to understand the super capacitive nature in presence and absence of light. We have synthesized and characterized our investigated materials by using FESEM, XRD, etc. Synthesized HPs have shown improved capacitive behavior and capacitance results and good operational stability owing to its slower ion kinetics. We fabricated electrodes by using a slurry through mixing of the active materials (perovskites) (70%), activated carbon (15%), and PVDF (15%) as a binder. onto a graphite sheet, followed by over-night drying at ∼70 °C under vacuum. Super capacitive behavior has been measured using electrochemical characterizations techniques such as galvanostatic charge discharge and cyclic voltammetry methods. The achieved specific capacitance values are 41 F/g, 18 F/g and 7.8 F/g at 0.1, 0.2 and 0.5 A/g current density, respectively. Preliminary research findings show promising results and good operational stability for 2D HPs based electrochemical supercapacitors. The operational stability can be attributed to the incorporation of hydrophobic organic ligands. Our work thus highlights the potential of unexplored 2D HPs as a futuristics supercapacitor material.

Keywords : Hybrid Halide Perovskites, Two-Dimensional, Energy Storage, Electrochemical Supercapacitors, Photo-Rechargeable.

Paper Submission Last Date
31 - May - 2026

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