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Kinetic and Mechanistic Investigation of Fructose with Ceric Ammonium Sulphate in Aqueous H2SO4


Authors : Lovely Sharma; Ghanshyam Upadhyay; M. P. Sah

Volume/Issue : Volume 11 - 2026, Issue 9 - September


Google Scholar : https://tinyurl.com/4avbew9y

DOI : https://doi.org/10.38124/ijisrt/26sep1261

Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.


Abstract : A kinetic investigation of the oxidation of fructose by Cerium(IV) in an aqueous sulphuric acid medium reveals that the reaction obeys first-order kinetics in both Ce(IV) and fructose. Increasing hydrogen ion concentration [H+] was found to lower the rate of reaction, and hydrogen sulphate ions likewise exert an inhibitory effect. The activation energy for the process has been determined, and a plausible mechanism is proposed in which Ce(IV) and fructose first combine to give an intermediate complex, whose slow decomposition constitutes the rate-determining step leading to the final products.

Keywords : Kinetics, Oxidation, Ce(IV), Fructose, Sulphuric Acid.

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A kinetic investigation of the oxidation of fructose by Cerium(IV) in an aqueous sulphuric acid medium reveals that the reaction obeys first-order kinetics in both Ce(IV) and fructose. Increasing hydrogen ion concentration [H+] was found to lower the rate of reaction, and hydrogen sulphate ions likewise exert an inhibitory effect. The activation energy for the process has been determined, and a plausible mechanism is proposed in which Ce(IV) and fructose first combine to give an intermediate complex, whose slow decomposition constitutes the rate-determining step leading to the final products.

Keywords : Kinetics, Oxidation, Ce(IV), Fructose, Sulphuric Acid.

Paper Submission Last Date
31 - October - 2026

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