Authors :
Lovely Sharma; Ghanshyam Upadhyay; M. P. Sah
Volume/Issue :
Volume 11 - 2026, Issue 9 - September
Google Scholar :
https://tinyurl.com/4avbew9y
DOI :
https://doi.org/10.38124/ijisrt/26sep1261
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Abstract :
A kinetic investigation of the oxidation of fructose by Cerium(IV) in an aqueous sulphuric acid medium reveals that the reaction obeys first-order kinetics in both Ce(IV) and fructose. Increasing hydrogen ion concentration [H+] was found to lower the rate of reaction, and hydrogen sulphate ions likewise exert an inhibitory effect. The activation energy for the process has been determined, and a plausible mechanism is proposed in which Ce(IV) and fructose first combine to give an intermediate complex, whose slow decomposition constitutes the rate-determining step leading to the final products.
Keywords :
Kinetics, Oxidation, Ce(IV), Fructose, Sulphuric Acid.
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A kinetic investigation of the oxidation of fructose by Cerium(IV) in an aqueous sulphuric acid medium reveals that the reaction obeys first-order kinetics in both Ce(IV) and fructose. Increasing hydrogen ion concentration [H+] was found to lower the rate of reaction, and hydrogen sulphate ions likewise exert an inhibitory effect. The activation energy for the process has been determined, and a plausible mechanism is proposed in which Ce(IV) and fructose first combine to give an intermediate complex, whose slow decomposition constitutes the rate-determining step leading to the final products.
Keywords :
Kinetics, Oxidation, Ce(IV), Fructose, Sulphuric Acid.