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Mineral Geochemical Implications in the Thermo-Barometric Conditions and Petrogenesis of the Bougouni Plutonic Complex, in Southern Mali (Léo-Man Shield, West African Craton)


Authors : Séko Sanogo; Salia Coulibaly; Dasso Yollande Traoré; Ousmane Wane; Cyril Durand; Michel Dubois; Adama Youssouf Koné

Volume/Issue : Volume 11 - 2026, Issue 8 - August


Google Scholar : https://tinyurl.com/bdfm38b9

DOI : https://doi.org/10.38124/ijisrt/26aug1198

Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.


Abstract : The Bougouni Pegmatite Province is recognized as the largest in west Africa. It comprises lithium-bearing pegmatites, which are associated with Paleoproterozoic rock lithology of Bougouni unit. In west Africa, the Paleoproterozoic rocks show alternation between metasedimentary units, greenstone belt and intrusive plutons. Plutonic intrusions are well distributed across the Léo-Man Shield and essential for understanding the evolution of Paleoproterozoic crust. This study highlight new petrographic and minerals chemical data of Bougouni unit. In this Unit,the metasedimentary rocks comprise two main types of metasedimentary sequence: coarse-grained (metagreywacke, schist and conglomerate) and fine-grained (siltstones and argillites). The Bougouni plutonic complex comprises a wide variety of rocks, range from diorite to two-mica monzogranites. They contain calcic amphibole, magnesium-rich biotite, plagioclase (albite to labrador), alkali feldspar (perthite, microcline), quartz, primary muscovite, and accessory minerals (e.g., titanite, magnetite, epidote, apatite, zircon etc.) in varying proportions.

Keywords : Mineral Chemistry; Crystallization; Magma Source; Thermometry; Barometry, Fugacity; Geodynamic Setting; WAC.

References :

  1. Abbott, R.N., 1985. Muscovite-bearing granites in the AFM liquidus projection. The Canadian Mineralogist 23, 553–561.
  2. Abbott, R.N., Clarke, D.B., 1979. Hypothetical liquidus relationships in the subsystem Al2O3-FeO-MgO projected from quartz, alkali feldspar and plagioclase for a (H2O)< or= 1. The Canadian Mineralogist, 17(3), 549-560 [WWW Document]. URL https://scholar.google.com/scholar?hl=fr&as_sdt=0%2C5&q=Hypothetical+liquidus+relationship+in+the+subsystemal&btnG=#d=gs_cit&t=1785524000066&u=%2Fscholar%3Fq%3Dinfo%3AggpkfbFoUYYJ%3Ascholar.google.com%2F%26output%3Dcite%26scirp%3D0%26hl%3Dfr (accessed 7.31.26).
  3. Abdel-Rahman, A.-F.M., 1994. Nature of Biotites from Alkaline, Calc-alkaline, and Peraluminous Magmas. Journal of Petrology 35, 525–541. https://doi.org/10.1093/petrology/35.2.525
  4. Abouchami, W., Boher, M., Michard, A., Albarede, F., 1990. A major 2.1 Ga event of mafic magmatism in west Africa: An Early stage of crustal accretion. Journal of Geophysical Research: Solid Earth 95, 17605–17629. https://doi.org/10.1029/JB095iB11p17605
  5. Andersen, D.J., Lindsley, D.H., Davidson, P.M., 1993. QUILF: A pascal program to assess equilibria among FeMgMnTi oxides, pyroxenes, olivine, and quartz. Computers & Geosciences 19, 1333–1350. https://doi.org/10.1016/0098-3004(93)90033-2
  6. Anderson, D.J., Lindsley, D.H., 1988. Internally consistent solution models for Fe-Mg-Mn-Ti oxides: Fe-Ti oxides. American Mineralogist 73, 714–726.
  7. Anderson, J.L., 1996. Status of thermobarometry in granitic batholiths. Earth and Environmental Science Transactions of the Royal Society of Edinburgh 87, 125–138. https://doi.org/10.1017/S0263593300006544
  8. Anderson, J.L., Barth, A.P., Wooden, J.L., Mazdab, F., 2008. Thermometers and thermobarometers in granitic systems. Reviews in Mineralogy and Geochemistry 69, 121–142. https://doi.org/10.2138/rmg.2008.69.4
  9. Anderson, J.L., Smith, D.R., 1995. The effects of temperature and fO2 on the Al-in-hornblende barometer. American Mineralogist 80, 549–559. https://doi.org/10.2138/am-1995-5-614
  10. Baratoux, L., Metelka, V., Naba, S., Jessell, M.W., Grégoire, M., Ganne, J., 2011. Juvenile Paleoproterozoic crust evolution during the Eburnean orogeny (∼2.2–2.0Ga), western Burkina Faso. Precambrian Research 191, 18–45. https://doi.org/10.1016/j.precamres.2011.08.010
  11. Bessoles, B., 1977. GEOLOGIE DE L’AFRIQUE. LE CRATON OUEST AFRICAIN.
  12. Black, R., Fabre, J., 1983. A BRIEF OUTLINE OF THE GEOLOGY OF WEST AFRICA. Afrique De L’ouest. Elsevier, 17–26. https://doi.org/10.1016/B978-0-08-030277-5.50006-7
  13. Blenkinsop, T.G., Oliver, N.H.S., Dirks, P.G.H.M., Nugus, M., Tripp, G., Sanislav, I., 2020. Chapter 1: Structural Geology Applied to the Evaluation of Hydrothermal Gold Deposits. In: Rowland, J.V., Rhys, D.A. (Eds.), APPLIED STRUCTURAL GEOLOGY OF ORE-FORMING HYDROTHERMAL SYSTEMS. Society of Economic Geologists, 1–23. https://doi.org/10.5382/rev.21.01
  14. Block, S., Jessell, M., Aillères, L., Baratoux, L., Bruguier, O., Zeh, A., Bosch, D., Caby, R., Mensah, E., 2016. Lower crust exhumation during Paleoproterozoic (Eburnean) orogeny, NW Ghana, West African Craton: Interplay of coeval contractional deformation and extensional gravitational collapse. Precambrian Research 274, 82–109. https://doi.org/10.1016/j.precamres.2015.10.014
  15. Boher, M., Abouchami, W., Michard, A., Albarede, F., Arndt, N.T., 1992. Crustal growth in West Africa at 2.1 Ga. Journal of Geophysical Research: Solid Earth 97, 345–369. https://doi.org/10.1029/91JB01640
  16. Botcharnikov, R.E., Koepke, J., Holtz, F., McCammon, C., Wilke, M., 2005. The effect of water activity on the oxidation and structural state of Fe in a ferro-basaltic melt. Geochimica et Cosmochimica Acta 69, 5071–5085. https://doi.org/10.1016/j.gca.2005.04.023
  17. Bowen, N.L., 1928. The Evolution of the Igneous Rocks., Princeton University Press. ed.
  18. Burnham, C.W., 1979. Magmas and hydrothermal fluids. in. Geochemistry of Hydrothermal Ore Deposits 71–136.
  19. Burnham, C.W., Holloway, J.R., Davis, N.F., 1969. Geological Society of America. [WWW Document]. URL https://scholar.google.com/scholar_lookup?title=Thermodynamic%20properties%20of%20water%20to%201000%C2%B0C%20and%2010%20000%20bars&journal=Geol%20Soc%20Am%2C%20Spec%20Pap&volume=132&pages=1-96&publication_year=1969&author=Burnham%2CCW&author=Holloway%2CJR&author=Davis%2CNF (accessed 8.12.26).
  20. Cahen, L., Snelling, N.J., Delhal, J., Vail, J.R., 1984. La géochronologie et l’évolution de l’Afrique. Clarendon Press, Oxford, 512., Clarendon Press.
  21. Cawthorn, R.G., O’Hara, M.J., 1976. Amphibole fractionation in calc-alkaline magma genesis. American Journal of Science 276, 309–329. https://doi.org/10.2475/ajs.276.3.309
  22. Cesare, B., Satish-Kumar, M., Cruciani, G., Pocker, S., Nodari, L., 2008. Mineral chemistry of Ti-rich biotite from pegmatite and metapelitic granulites of the Kerala Khondalite Belt (southeast India): Petrology and further insight into titanium substitutions. American Mineralogist 93, 327–338. https://doi.org/10.2138/am.2008.2579
  23. Chappell, B.W., White, A.J.R., 1992. I- and S-type granites in the Lachlan Fold Belt. Earth and Environmental Science Transactions of the Royal Society of Edinburgh 83, 1–26. https://doi.org/10.1017/S0263593300007720
  24. Coltorti, M., Dramis, F., Ollier, C., 2007. Planation surfaces in Northern Ethiopia. Geomorphology 89, 287–296. https://doi.org/10.1016/j.geomorph.2006.12.007
  25. De Kock, G.S., Théveniaut, H., Botha, P.M.W., Gyapong, W., 2012. Timing the structural events in the Palaeoproterozoic Bolé–Nangodi belt terrane and adjacent Maluwe basin, West African craton, in central-west Ghana. Journal of African Earth Sciences 65, 1–24. https://doi.org/10.1016/j.jafrearsci.2011.11.007
  26. De Oliveira, V.E.S., De Oliveira, D.C., Marangoanha, B., Lamarão, C.N., 2018. Geology, mineralogy and petrological affinities of the Neoarchean granitoids from the central portion of the Canaã dos Carajás domain, Amazonian craton, Brazil. Journal of South American Earth Sciences 85, 135–159. https://doi.org/10.1016/j.jsames.2018.04.022
  27. Deer, W.A., Howie, R.A., Zussman, Jack, Zussman, J., 1992. An Introduction to the Rock-forming Minerals. Longman Scientific & Technical.
  28. Devine, J.D., Rutherford, M.J., Norton, G.E., Young, S.R., 2003. Magma Storage Region Processes Inferred from Geochemistry of Fe-Ti Oxides in Andesitic Magma, Soufriere Hills Volcano, Montserrat, W.I. Journal of Petrology 44, 1375–1400. https://doi.org/10.1093/petrology/44.8.1375
  29. Dymek, R.F., 1983. Titanium, aluminum and interlayer cation substitutions in biotite from high-grade gneisses, west Greenland. American Mineralogist 68, 880–899.
  30. Eisenlohr, B.N., Hirdes, W., 1992. The structural development of the early Proterozoic Birimian and tarkwaian rocks of southwest Ghana, West Africa. Journal of African Earth Sciences (and the Middle East) 14, 313–325. https://doi.org/10.1016/0899-5362(92)90035-B
  31. El-Awady, A., Sami, M., Abart, R., Fathy, D., Farahat, E.S., Ahmed, M.S., Osman, H., Ragab, A., 2024. Petrogenesis and Tectonic Evolution of I- and A-Type Granites of Mount Abu Kibash and Tulayah, Egypt: Evidence for Transition from Subduction to Post-Collision Magmatism. Minerals 14, 806. https://doi.org/10.3390/min14080806
  32. Ellis, D.J., Thompson, A.B., 1986. Subsolidus and Partial Melting Reactions in the Quartz-excess CaO+MgO+Al2O3+SiO2+H2O System under Water-excess and Water-deficient Conditions to 10 kb: Some Implications for the Origin of Peraluminous Melts from Mafic Rocks. Journal of Petrology 27, 91–121. https://doi.org/10.1093/petrology/27.1.91
  33. Ennih, N., Liégeois, J.-P., 2008. The boundaries of the West African craton, with special reference to the basement of the Moroccan metacratonic Anti-Atlas belt. Geological Society, London, Special Publications 297, 1–17. https://doi.org/10.1144/SP297.1
  34. Eskola, P., 1915. On the relations between the chemical and mineralogical composition in the metamorphic rocks of the Orijarvi region., Bulletin de la Commission géologique de Finlande.
  35. Feybesse, J.-L., Billa, M., Guerrot, C., Duguey, E., Lescuyer, J.-L., Milesi, J.-P., Bouchot, V., 2006. The paleoproterozoic Ghanaian province: Geodynamic model and ore controls, including regional stress modeling. Precambrian Research 149, 149–196. https://doi.org/10.1016/j.precamres.2006.06.003
  36. Feybesse, J.-L., Sidibé, Y.T., Konaté, C.M., Lacomme, A., Zammit, C., Guerrot, C., Liégeois, J.-P., De Waelle, B., 2006. Notice explicative de la carte géologique de la République du Mali à 1/200000, Feuille n°NC-29-XVII, Tienko, Bamako (Mali) Ministère des mines, de l’Energie et de l’Eau, 2006. 32 p. - References - Scientific Research Publishing [WWW Document]. URL https://www.scirp.org/reference/referencespapers?referenceid=2972819 (accessed 9.1.25).
  37. France, L., Koepke, J., Ildefonse, B., Cichy, S.B., Deschamps, F., 2010. Hydrous partial melting in the sheeted dike complex at fast spreading ridges: experimental and natural observations. Contributions to Mineralogy and Petrology 160, 683–704. https://doi.org/10.1007/s00410-010-0502-6
  38. Ghent, E.D., Nicholls, J., Simony, P.S., Sevigny, J.H., Stout, M.Z., 1991. Hornblende geobarometry of the Nelson Batholith, southeastern British Columbia: tectonic implications. Canadian Journal of Earth Sciences 28, 1982–1991. https://doi.org/10.1139/e91-180
  39. Gill, J.B., 1981. Orogenic Andesites and Plate Tectonics, Minerals and Rocks. Springer Berlin Heidelberg, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-68012-0
  40. Goranson, 1931. Solubility of water in granite magmas. Eos, Transactions American Geophysical Union 12, 183–183. https://doi.org/10.1029/TR012i001p00183-1
  41. Grenholm, M., Jessell, M., Thébaud, N., 2019. A geodynamic model for the Paleoproterozoic (ca. 2.27–1.96 Ga) Birimian Orogen of the southern West African Craton – Insights into an evolving accretionary-collisional orogenic system. Earth-Science Reviews 192, 138–193. https://doi.org/10.1016/j.earscirev.2019.02.006
  42. Hammarstrom, J.M., Zen, E., 1986. Aluminum in hornblende: An empirical igneous geobarometer. American Mineralogist 71, 1297–1313.
  43. Hawthorne, F.C., Oberti, R., Harlow, G.E., Maresch, W.V., Martin, R.F., Schumacher, J.C., Welch, M.D., 2012. Nomenclature of the amphibole supergroup. American Mineralogist 97, 2031–2048. https://doi.org/10.2138/am.2012.4276
  44. Hein, K.A.A., 2010. Succession of structural events in the Goren greenstone belt (Burkina Faso): Implications for West African tectonics. Journal of African Earth Sciences 56, 83–94. https://doi.org/10.1016/j.jafrearsci.2009.06.002
  45. Henry, D.J., Guidotti, C.V., Thomson, J.A., 2005. The Ti-saturation surface for low-to-medium pressure metapelitic biotites: Implications for geothermometry and Ti-substitution mechanisms. American Mineralogist 90, 316–328. https://doi.org/10.2138/am.2005.1498
  46. Hoisch, T.D., 1989. A muscovite-biotite geothermometer | American Mineralogist, vol. 74, no 5‑6, p. 565‑572 [WWW Document]. URL https://pubs.geoscienceworld.org/msa/ammin/article-abstract/74/5-6/565/42230/A-muscovite-biotite-geothermometer (accessed 7.31.26).
  47. Holland, T., Blundy, J., 1994. Non-ideal interactions in calcic amphiboles and their bearing on amphibole-plagioclase thermometry. Contributions to Mineralogy and Petrology 116, 433–447. https://doi.org/10.1007/BF00310910
  48. Hollister, L.S., Grissom, G.C., Peters, E.K., Stowell, H.H., Sisson, V.B., Hollister, L.S., Grissom, G.C., Peters, E.K., Stowell, H.H., Sisson, V.B., 1987. Confirmation of the empirical correlation of Al in hornblende with pressure of solidification of calc-alkaline plutons. American Mineralogist 72, 231–239.
  49. Holtz, F., Johannes, W., Tamic, N., Behrens, H., 2001. Maximum and minimum water contents of granitic melts generated in the crust: a reevaluation and implications. Lithos, Prograde and Retrograde Processes in Crustal Melting 56, 1–14. https://doi.org/10.1016/S0024-4937(00)00056-6
  50. Ikenne, M., Söderlund, U., Ernst, R.E., Pin, C., Youbi, N., El Aouli, E.H., Hafid, A., 2017. A c. 1710 Ma mafic sill emplaced into a quartzite and calcareous series from Ighrem, Anti-Atlas – Morocco: Evidence that the Taghdout passive margin sedimentary group is nearly 1 Ga older than previously thought. Journal of African Earth Sciences 127, 62–76. https://doi.org/10.1016/j.jafrearsci.2016.08.020
  51. Ishihara, 1977. The magnetite-series and ilmenite-series granitic rocks. https://doi.org/10.11456/shigenchishitsu1951.27.293
  52. Jiang, C., An, S., 1984. On chemical characteristics of calcific amphiboles from igneous rocks and their petrogenesis significance. Journal of Mineralogy and Petrology 3: 1-9.
  53. Johnson, M.C., Rutherford, M.J., 1989a. Experimental calibration of the aluminum-in-hornblende geobarometer with application to Long Valley caldera (California) volcanic rocks. Geology 17, 837. https://doi.org/10.1130/0091-7613(1989)017%3C0837:ECOTAI%3E2.3.CO;2
  54. Johnson, M.C., Rutherford, M.J., 1989b. Experimental calibration of the aluminum-in-hornblende geobarometer with application to Long Valley caldera (California) volcanic rocks. Geology 17, 837. https://doi.org/10.1130/0091-7613(1989)017%3C0837:ECOTAI%3E2.3.CO;2
  55. Kouamelan, A.-N., 1996. Géochronologie et Géochimie des Formations Archéennes et Protérozoïques de la Dorsale de Man en Côte d’Ivoire. Implications pour la Transition Archéen-Protéozoïque. phdthesis. Université Rennes 1.
  56. Kouamelan, A.N., Delor, C., Peucat, J.-J., 1997. Geochronological evidence for reworking of Archean terrains during the Early Proterozoic (2.1 Ga) in the western Coˆte d’Ivoire (Man Rise-West African Craton). Precambrian Research 86, 177–199. https://doi.org/10.1016/S0301-9268(97)00043-0
  57. Laird, J., Albee, A.L., 1981. High-pressure metamorphism in mafic schist from northern Vermont. American Journal of Science 281, 97–126. https://doi.org/10.2475/ajs.281.2.97
  58. Lalonde, A.E., Bernard, P., 1993. Composition and color of biotite from granites; two useful properties in characterization of plutonic suites from the Hepburn internal zone of Wopmay Orogen, Northwest Territories. The Canadian Mineralogist 31, 203–217.
  59. Lasheen, E.S.R., Saleh, G.M., El-Tohamy, A., Khaleal, F.M., Sami, M., Sanislav, I.V., Abdalla, F., 2025. Mineral Chemistry and Whole-Rock Analysis of Magnesian and Ferroan Granitic Suites of Magal Gebreel, South Eastern Desert: Clues for Neoproterozoic Syn- and Post-Collisional Felsic Magmatism. Minerals 15, 751. https://doi.org/10.3390/min15070751
  60. Leake, B.E., Woolley, A.R., Arps, C.E.S., Birch, W.D., Gilbert, M.C., Grice, J.D., Hawthorne, E., Kato, A., Kisch, H.J., Krivovichev, V.G., Linthout, K., Laird, J., Mandarino, J., Maresch, W.V., Nickel, E.H., Rock, N.M.S., Schumacher, J.C., Smith, D.C., Stephenson, N.C.N., Ungaretti, L., Whittaker, E.J.W., Youzhi, G., 1997. Nomenclature of amphiboles Report of the Subcommittee on Amphiboles of the International Mineralogical Association Commission on New Minerals and Mineral Names. European Journal of Mineralogy 623–651. https://doi.org/10.1127/ejm/9/3/0623
  61. Liao, Y., Wei, C., Rehman, H.U., 2021. Titanium in calcium amphibole: Behavior and thermometry. American Mineralogist 106, 180–191. https://doi.org/10.2138/am-2020-7409
  62. Liégeois, J.P., Claessens, W., Camara, D., Klerkx, J., 1991. Short-lived Eburnian orogeny in southern Mali. Geology, tectonics, U-Pb and Rb-Sr geochronology. Precambrian Research 50, 111–136. https://doi.org/10.1016/0301-9268(91)90050-K
  63. Loiselle, M.C., Wones, D.R., 1979. characteristics of Anorogenic granites. Geological Society of America 11, 468. Abstracts with Programs.
  64. Lompo, M., 2010. Paleoproterozoic structural evolution of the Man-Leo Shield (West Africa). Key structures for vertical to transcurrent tectonics. Journal of African Earth Sciences 58, 19–36. https://doi.org/10.1016/j.jafrearsci.2010.01.005
  65. Masurel, Q., Eglinger, A., Thébaud, N., Allibone, A., André-Mayer, A.-S., McFarlane, H., Miller, J., Jessell, M., Aillères, L., Vanderhaeghe, O., Salvi, S., Baratoux, L., Perrouty, S., Begg, G., Fougerouse, D., Hayman, P., Wane, O., Tshibubudze, A., Parra-Avila, L., Kouamélan, A., Amponsah, P.O., 2022. Paleoproterozoic gold events in the southern West African Craton: review and synopsis. Mineralium Deposita 57, 513–537. https://doi.org/10.1007/s00126-021-01052-5
  66. Milési, J.-P., Ledru, P., Feybesse, J.-L., Dommanget, A., Marcoux, E., 1992. Early proterozoic ore deposits and tectonics of the Birimian orogenic belt, West Africa. Precambrian Research 58, 305–344. https://doi.org/10.1016/0301-9268(92)90123-6
  67. Munoz, J.L., 1984. F-OH and Cl-OH exchange in micas with applications to hydrothermal ore deposits,Reviews in Mineralogy and Geochemistry, vol. 13, no 1, p. 469‑493.
  68. Munoz, L.J., 1992. Calculation of HF and HCl fugacities from biotite compositions : re-vised equations, Geol. Soc. Am., Abstract Programs, vol. 24, p. A221, [WWW Document]. URL https://cir.nii.ac.jp/crid/1571135650474665984 (accessed 7.31.26).
  69. Mutch, E., Blundy, J., Tattitch, B., Cooper, F., Brooker, R., 2016. An experimental study of amphibole stability in low-pressure granitic magmas and a revised Al-in-hornblende geobarometer. https://doi.org/10.17863/CAM.6362
  70. Nachit, H., Ibhi, A., Abia, E.H., Ben Ohoud, M., 2005. Discrimination between primary magmatic biotites, reequilibrated biotites and neoformed biotites. Comptes Rendus. Géoscience 337, 1415–1420. https://doi.org/10.1016/j.crte.2005.09.002
  71. Nyarko, E.S., 2010. Geochemistry of Basin-type granitoids in the Winneba area.
  72. Nyarko, E.S., Aseidu, D.K., Osea, S., Dampare, S., Zakaria, N., Hanson, J., Osei, J., Enti-Brown, S., Tulasi, D., 2012. Geochemical characteristics of the basin-type granitoids in the Winneba Area of Ghana.
  73. Nzolang, C., 2005. Crustal Evolution of the Precambrian Basement in West Cameroon Inference from Geochemistry, Sr-Nd Isotopes and Experimental Investigation of Some Granitoids and Metamorphic Rocks. Niigata University, Niigata, Japan. - References - Scientific Research Publishing [WWW Document]. URL https://www.scirp.org/reference/referencespapers?referenceid=3120963 (accessed 9.3.25).
  74. Petersson, A., Scherstén, A., Kemp, A.I.S., Kristinsdóttir, B., Kalvig, P., Anum, S., 2016. Zircon U–Pb–Hf evidence for subduction related crustal growth and reworking of Archaean crust within the Palaeoproterozoic Birimian terrane, West African Craton, SE Ghana. Precambrian Research 275, 286–309. https://doi.org/10.1016/j.precamres.2016.01.006
  75. Pirajno, F., 2009. Water and Hydrothermal Fluids on Earth. In: Pirajno, F. (Ed.), Hydrothermal Processes and Mineral Systems. Springer Netherlands, Dordrecht, 1–71. https://doi.org/10.1007/978-1-4020-8613-7_1
  76. Piwinskii, A.J., 1973. Experimental studies of granitoids from the Central and Southern Coast Ranges, California. TMPM Tschermaks Mineralogische Und Petrographische Mitteilungen 20, 107–130. https://doi.org/10.1007/BF01081387
  77. Potrel, A., Peucat, J.J., Fanning, C.M., Auvray, B., Burg, J.P., Caruba, C., 1996. 3.5 Ga old terranes in the West African Craton, Mauritania. Journal of the Geological Society 153, 507–510. https://doi.org/10.1144/gsjgs.153.4.0507
  78. Putirka, K., 2016. Amphibole thermometers and barometers for igneous systems and some implications for eruption mechanisms of felsic magmas at arc volcanoes. American Mineralogist 101, 841–858. https://doi.org/10.2138/am-2016-5506
  79. Raase, P., 1974. Al and Ti contents of hornblende, indicators of pressure and temperature of regional metamorphism. Contributions to Mineralogy and Petrology 45, 231–236. https://doi.org/10.1007/BF00383440
  80. Ridolfi, F., Renzulli, A., 2012. Calcic amphiboles in calc-alkaline and alkaline magmas: thermobarometric and chemometric empirical equations valid up to 1,130°C and 2.2 GPa. Contributions to Mineralogy and Petrology 163, 877–895. https://doi.org/10.1007/s00410-011-0704-6
  81. Ridolfi, F., Renzulli, A., Puerini, M., 2010. Stability and chemical equilibrium of amphibole in calc-alkaline magmas: an overview, new thermobarometric formulations and application to subduction-related volcanoes. Contributions to Mineralogy and Petrology 160, 45–66. https://doi.org/10.1007/s00410-009-0465-7
  82. Ridolfi, L., D’Odorico, P., Laio, F., Tamea, S., Rodriguez‐Iturbe, I., 2008. Coupled stochastic dynamics of water table and soil moisture in bare soil conditions. Water Resources Research 44, 2007WR006707. https://doi.org/10.1029/2007WR006707
  83. Rieder, M., Cavazzini, G., D’yakonov, Y.S., Frank-Kamenetskii, V.A., Gottardi, G., Guggenheim, S., Koval’, P.V., Müller, G., Neiva, A.M.R., Radoslovich, E.W., Robert, J.-L., Sassi, F.P., Takeda, H., Weiss, Z., Wones, D.R., 1999. Nomenclature of the micas. Mineralogical Magazine 63, 267–279. https://doi.org/10.1180/minmag.1999.063.2.13
  84. Robb, L., 2005. Introduction to Ore-Forming Processes. Blackwell Sciences Ltd., 376 p. - References - Scientific Research Publishing [WWW Document]. URL https://www.scirp.org/reference/referencespapers?referenceid=4030577 (accessed 9.6.25).
  85. Rocci, G., Bronner, G., Deschamps, M., 1991. Crystalline Basement of the West African Craton. In: Dallmeyer, R.D., Lécorché, J.P. (Eds.), The West African Orogens and Circum-Atlantic Correlatives. Springer Berlin Heidelberg, Berlin, Heidelberg, 31–61. https://doi.org/10.1007/978-3-642-84153-8_3
  86. Sami, M., Osman, H., Ahmed, A.F., Zaky, K.S., Abart, R., Sanislav, I.V., Abdelrahman, K., Fnais, M.S., Xiao, W., Abbas, H., 2023. Magmatic Evolution and Rare Metal Mineralization in Mount El-Sibai Peralkaline Granites, Central Eastern Desert, Egypt: Insights from Whole-Rock Geochemistry and Mineral Chemistry Data. Minerals 13, 1039. https://doi.org/10.3390/min13081039
  87. Sanogo, S., 2022. Pegmatites lithinifères (Li-Cs-Ta) et roches plutoniques de Bougouni (Sud du Mali, Craton Ouest Africain) : approches pétrographiques, structurales, géochimiques et géochronologiques. Doctorat ès Sciences de la terre et de l’univers, PhD. Université de Lille (2022-....). https://doi.org/10.70675/edffdafazc4c3z48b3z8ac1ze712e93c8265
  88. Sanogo, S., Koné, A.Y., Wane, O., Durand, C., Dubois, M., 2025. Mapping of Lithium-Bearing Pegmatites Using Aeromagnetic Data and Field Outcrop Descriptions in the Bougouni Area, Southern Mali. Geomaterials 15, 57–81. https://doi.org/10.4236/gm.2025.152004
  89. Sanogo, S., Wane, O., Dembele, A., Durand, C., Dubois, M., 2026. Update to the structural analysis of the Bougouni Pegmatite Province (BPP), southern Mali: Formation mechanism of lithiniferous pegmatites. Journal of Structural Geology 210, 105761. https://doi.org/10.1016/j.jsg.2026.105761
  90. Schmidt, M.W., 1992. Amphibole composition in tonalite as a function of pressure: an experimental calibration of the Al-in-hornblende barometer. Contributions to Mineralogy and Petrology 110, 304–310. https://doi.org/10.1007/BF00310745
  91. Sisson, T.W., Grove, T.L., 1993. Experimental investigations of the role of H2O in calc-alkaline differentiation and subduction zone magmatism. Contributions to Mineralogy and Petrology 113, 143–166. https://doi.org/10.1007/BF00283225
  92. Spear, F.S., 1981. An experimental study of hornblende stability and compositional variability in amphibolite. American Journal of Science 281, 697–734. https://doi.org/10.2475/ajs.281.6.697
  93. Streckeisen, A., 1976. To each plutonic rock its proper name. Earth-Science Reviews 12, 1–33. https://doi.org/10.1016/0012-8252(76)90052-0
  94. Terry, R.D., Chilingar, G.V., 1955. Comparison charts for visual estimation of percent composition. Allen Hancock Foundation, Los Angeles, Calif. Reprinted from J. Sed. Petrology,. 226–234.
  95. Thiéblemont, D., Goujou, J.C., Egal, E., Cocherie, A., Delor, C., Lafon, J.M., Fanning, C.M., 2004. Archean evolution of the Leo Rise and its Eburnean reworking. Journal of African Earth Sciences 39, 97–104. https://doi.org/10.1016/j.jafrearsci.2004.07.059
  96. Thiéblemont, D., Liégeois, J.P., Fernandez-Alonso, M., Ouabadi, A., Le Gall, B., Maury, R., Jalludin, M., Vidal, M., Ouattara Gbélé, C., Tchaméni, R., Michard, A., Nehlig, P., Rossi, P., Chêne, F., 2016. Geological map of Africa - CCGM.
  97. Thomas, M.J., Loader, M.A., Wilkinson, J.J., Buret, Y., Large, S.J.E., Birt, E.A., 2023. The Strontian Intrusive Complex: Petrography, Thermobarometry and the Influence of Titanite on Residual Melt Chemistry. Journal of Petrology 64, egad059. https://doi.org/10.1093/petrology/egad059
  98. Traore, E.M., Olatunji, A.S., Sidibe, M., Konate, S.I.M., Kouagou N’dah, N.D., Lemewihbwen Ngiamte, G., 2026. Geological setting, geochemistry and mineralogy of lithium bearing pegmatites in South Western Mali, West Africa; a review. Geology, Ecology, and Landscapes 10, 371–393. https://doi.org/10.1080/24749508.2025.2449623
  99. Traoré, K., Chardon, D., Naba, S., Wane, O., Bouaré, M.L., 2022. Paleoproterozoic collision tectonics in West Africa: Insights into the geodynamics of continental growth. Precambrian Research 376, 106692. https://doi.org/10.1016/j.precamres.2022.106692
  100. Tshibubudze, A., Hein, K.A.A., Peters, L.F.H., Woolfe, A.J., McCUAIG, T.C., 2013. OLDEST U-PB CRYSTALLISATION AGE FOR THE WEST AFRICAN CRATON FROM THE OUDALAN-GOROUOL BELT OF BURKINA FASO. South African Journal of Geology 116, 169–181. https://doi.org/10.2113/gssajg.116.1.169
  101. Turner, D.C., 1983. Upper Proterozoic schist belts in the Nigerian sector of the Pan-African Province of West Africa. Precambrian Research 21, 55–79. https://doi.org/10.1016/0301-9268(83)90005-0
  102. Tuttle, O.F., Bowen, N.L., 1958. Origin of granite in the light of experimental studies in the system NaAlSi3O8-KAlSi3O8-SiO2-H2O [WWW Document]. URL https://dggs.alaska.gov/pubs/id/30725 (accessed 8.12.26).
  103. Uchida, E., Endo, S., Makino, M., 2007a. Relationship Between Solidification Depth of Granitic Rocks and Formation of Hydrothermal Ore Deposits. Resource Geology 57, 47–56. https://doi.org/10.1111/j.1751-3928.2006.00004.x
  104. Uchida, E., Endo, S., Makino, M., 2007b. Relationship Between Solidification Depth of Granitic Rocks and Formation of Hydrothermal Ore Deposits. Resource Geology 57, 47–56. https://doi.org/10.1111/j.1751-3928.2006.00004.x
  105. Wane, O., 2010. Étude géologique du Birimien de la région de Massigui (Paléoprotérozoïque du Mali méridional) : la zone de cisaillement du Banifing, structure majeure du craton ouest-africain. These de doctorat. Lille 1.
  106. Wane, O., Liégeois, J.-P., Thébaud, N., Miller, J., Metelka, V., Jessell, M., 2018. The onset of the Eburnean collision with the Kenema-Man craton evidenced by plutonic and volcanosedimentary rock record of the Masssigui region, southern Mali. Precambrian Research 305, 444–478. https://doi.org/10.1016/j.precamres.2017.11.008
  107. Wane, O., Ouologuem, A.B., N’diaye, I., Dao, O., Yossi, M., 2021. Petro-Structural Study of the Paleoproterozoic Formations of the Faboula Gold Deposit (Bougouni-K&#233;koro Basin, Leo-Man Shield). Open Journal of Geology 11, 105–141. https://doi.org/10.4236/ojg.2021.114007
  108. Wilde, A., Otto, A., McCracken, S., 2021. Geology of the Goulamina spodumene pegmatite field, Mali. Ore Geology Reviews 134, 104162. https://doi.org/10.1016/j.oregeorev.2021.104162
  109. Winkler, G.C., 1979. Petrogenesisof metamorphic rocks. 348.
  110. Wones, D.R., 1989. Significance of the assemblage titanite+magnetite+quartz in granitic rocks. American Mineralogist 74, 744–749.
  111. Wu, C.-M., 2020. Calibration of the biotite-muscovite geobarometer for metapelitic assemblages devoid of garnet or plagioclase. Lithos 372–373, 105668. https://doi.org/10.1016/j.lithos.2020.105668
  112. Wu, C.-M., Chen, H.-X., 2015. Revised Ti-in-biotite geothermometer for ilmenite- or rutile-bearing crustal metapelites. Science Bulletin 60, 116–121. https://doi.org/10.1007/s11434-014-0674-y
  113. Wyllie, P.J., 1978. Water and magma generation at subduction zones. Bulletin Volcanologique 41, 360–377. https://doi.org/10.1007/BF02597371
  114. Wyllie, P.J., Huang, W.-L., 1976. Carbonation and melting reactions in the system CaO?MgO?SiO2?CO2 at mantle pressures with geophysical and petrological applications. Contributions to Mineralogy and Petrology 54, 79–107. https://doi.org/10.1007/BF00372117
  115. Yoder, H.S., 1955. Role of Water in Metamorphism. In: Poldervaart, A. (Ed.), Crust of the Earth: A Symposium. Geological Society of America, 505–524. https://doi.org/10.1130/SPE62-p505
  116. Zhou, J.K., 1986. Differential transformation and its applications for electrical circuits. Huazhong University Press, Wuhan, China.

The Bougouni Pegmatite Province is recognized as the largest in west Africa. It comprises lithium-bearing pegmatites, which are associated with Paleoproterozoic rock lithology of Bougouni unit. In west Africa, the Paleoproterozoic rocks show alternation between metasedimentary units, greenstone belt and intrusive plutons. Plutonic intrusions are well distributed across the Léo-Man Shield and essential for understanding the evolution of Paleoproterozoic crust. This study highlight new petrographic and minerals chemical data of Bougouni unit. In this Unit,the metasedimentary rocks comprise two main types of metasedimentary sequence: coarse-grained (metagreywacke, schist and conglomerate) and fine-grained (siltstones and argillites). The Bougouni plutonic complex comprises a wide variety of rocks, range from diorite to two-mica monzogranites. They contain calcic amphibole, magnesium-rich biotite, plagioclase (albite to labrador), alkali feldspar (perthite, microcline), quartz, primary muscovite, and accessory minerals (e.g., titanite, magnetite, epidote, apatite, zircon etc.) in varying proportions.

Keywords : Mineral Chemistry; Crystallization; Magma Source; Thermometry; Barometry, Fugacity; Geodynamic Setting; WAC.

Paper Submission Last Date
31 - October - 2026

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