New Age Batteries: Recent Breakthroughs in Sodium-Ion Battery Technology


Authors : Kavy N Panchal

Volume/Issue : Volume 9 - 2024, Issue 10 - October


Google Scholar : https://tinyurl.com/2fucme5y

Scribd : https://tinyurl.com/mr2vnuph

DOI : https://doi.org/10.5281/zenodo.14355107


Abstract : In this race to a decarbonized energy landscape, sodium-ion batteries have been pursued as a sustainable alternative to lithium-ion batteries. The abundance of the element, reduced production costs, and smaller impact on the environment compared to Li make SIBs a possible solution for large-scale energy storage. This work focuses on the current main components of SIBs, which include cathodes like layered transition metal oxides and Prussian blue analogues, and some state-of- the-art materials such as lithium-doped tunnel-type cathodes. Anodes include disodium terephthalate/multi- walled carbon nanotube composites and flash-pyrolyzed coal char that are discussed for the enhancement of their sodium storage capabilities. The performance assessment due to these different electrolytes is presented, among which are ethyl acetate-based ones and some solid-state NASICONs. Although challenges such as the low energy density and dendrite formation exist, ongoing research focuses on enhancing the lifespan, safety, and cost- effectiveness of SIBs so that broad adoption in a sustainable energy storage solution is achieved.

Keywords : Sodium-Ion Batteries (Sibs), Decarbonized Energy, Sustainable Energy Storage, Layered Transition Metal Oxides, Prussian Blue Analogues, Lithium-Doped Cathodes, Disodium Terephthalate/Multi-Walled Carbon Nanotube Composites, Flash-Pyrolyzed Coal Char, Ethyl Acetate-Based Electrolytes, Solid-State NASICON Electrolytes, Energy Density, Dendrite Formation.

References :

  1. Cao, F., Gao, G.W., Feng, Y., Getachew, B.A., & Wang, T.G. (2022). Electrochemical Properties of Metallic Coatings.
  2. Chang, X., Yang, Z., Liu, Y., Chen, J., Wu, M., Li, L., Chou, S., & Qiao, Y. (2024). The guarantee of large-scale energy storage: Non-flammable organic liquid electrolytes for high-safety sodium ion batteries. Energy Storage Materials, 103407. https://doi.org/10.1016/j.ensm.2024.103407
  3. Elisa. (2023, August 1). Sodium batteries: The technology of the future? Flash Battery. https://www.flashbattery.tech/en/sodium-batteries/
  4. Goikolea, E., Palomares, V., Wang, S., De Larramendi, I. R., Guo, X., Wang, G., & Rojo, T. (2020). Na‐Ion Batteries—Approaching old and new challenges. Advanced Energy Materials, 10(44). https://doi.org/10.1002/aenm.202002055
  5. Gupta, P., Pushpakanth, S., Haider, M. A., & Basu, S. (2022). Understanding the design of Cathode materials for Na-Ion batteries. ACS Omega, 7(7), 5605–5614. https://doi.org/10.1021/acsomega.1c05794
  6. Han, C., Xin, L., Wu, Z., Li, M., Long, H., & Gao, X. (2023). Preparation of disodium terephthalate/multi-walled carbon nanotube composite as an anode material for sodium-ion batteries: Performance and mechanism. Materials Chemistry and Physics, 308, 128272. https://doi.org/10.1016/j.matchemphys.2023.128272
  7. He, Z., Huang, Y., Liu, H., Geng, Z., Li, Y., Li, S., Deng, W., Zou, G., Hou, H., & Ji, X. (2024). Anode materials for fast charging sodium-ion batteries. Nano Energy, 109996. https://doi.org/10.1016/j.nanoen.2024.109996
  8. Huang, B., Cheng, L., Li, X., Zhao, Z., Yang, J., Li, Y., Pang, Y., & Cao, G. (2022). Layered Cathode Materials: Precursors, Synthesis, Microstructure, Electrochemical Properties, and Battery Performance. Small, e2107697.
  9. Liu, L., Xu, Q., Yin, S., Liu, Z., Li, Y., & Pang, W. (2024). Recent progress on hard carbon-based anode for sodium-ion battery. Journal of Power Sources, 615, 235116. https://doi.org/10.1016/j.jpowsour.2024.235116
  10. Liu, M., Xu, J., Shao, L., Shi, X., Li, C., & Sun, Z. (2024). Towards metal selenides: a promising anode for sodium-ion batteries. Chemical Communications, 60(54), 6860–6872. https://doi.org/10.1039/d4cc01974a
  11. Manthiram, A., Fu, Y., Chung, S.-H., & Zu, C. (2014). Challenges and opportunities for sodium-ion batteries. Chemical Reviews, 114(23), 11751-11787.
  12. Nguyen, T. P., & Kim, I. T. (2023). Recent advances in Sodium-Ion Batteries: Cathode materials. Materials, 16(21), 6869. https://doi.org/10.3390/ma16216869
  13. Palomares, E., Gonzáles-Calbet, J., Ares, J. R., & Rojo, T. (2012). Na-ion batteries: Progress and challenges. Advanced Materials, 24(41), 5446-5460.
  14. Ransford, C. &. (2024, June 4). Patenting sodium-ion batteries: the challenges faced as commercialisation progresses. Carpmaels & Ransford. https://www.carpmaels.com/patenting-sodium-ion-batteries-the-challenges-faced-as-commercialisation-progresses/
  15. Shi, W., Li, H., Zhang, D., Du, F., Zhang, Y., Wang, Z., Zhang, X., & Zhang, P. (2023). Insights into unrevealing the effects of the monovalent cation substituted tunnel-type cathode for high-performance sodium-ion batteries. Chemical Engineering Journal, 477, 146976. https://doi.org/10.1016/j.cej.2023.146976
  16. Thomas, J. (2024, April 3). Are sodium-ion batteries the solution for EVs? Innovation News Network. https://www.innovationnewsnetwork.com/are-sodium-ion-batteries-the-solution-for-evs/44177/
  17. Xu, P., Yuan, Q., Ji, W., Yu, R., Wang, F., & Huo, N. (2022). Study on the annealing phase transformation mechanism and electrochemical properties of carbon submicron fibers loaded with cobalt. Materials Express.
  18. Zhang, L., Xia, Y., Yang, H., Xiao, S., Zhou, J., Cao, Y., & Qian, T. (2022). The current status of sodium metal anodes for improved sodium batteries and its future perspectives. APL Materials, 10(7). https://doi.org/10.1063/5.0097264
  19. Synthesis of Fe-doped Mn-based Prussian blue hierarchical architecture for high-performance sodium ion batteries. (n.d.). https://ouci.dntb.gov.ua/en/works/7Prz1L1l/
  20. Shi, W., Li, H., Zhang, D., Du, F., Zhang, Y., Wang, Z., Zhang, X., & Zhang, P. (2023). Insights into unrevealing the effects of the monovalent cation substituted tunnel-type cathode for high-performance sodium-ion batteries. Chemical Engineering Journal, 477, 146976. https://doi.org/10.1016/j.cej.2023.146976
  21. Parveen, S., & Hashmi, S. (2023). Flexible gel polymer electrolyte comprising high flash point solvent adiponitrile with ethylene carbonate as co-solvent for sodium-ion batteries. Journal of Energy Storage, 67, 107519. https://doi.org/10.1016/j.est.2023.107519
  22. Yabuuchi, N., Kubota, K., Dahbi, M., & Komaba, S. (2014). Research development on Sodium-Ion batteries. Chemical Reviews, 114(23), 11636–11682. https://doi.org/10.1021/cr500192f
  23. Han, C., Xin, L., Wu, Z., Li, M., Long, H., & Gao, X. (2023). Preparation of disodium terephthalate/multi-walled carbon nanotube composite as an anode material for sodium-ion batteries: Performance and mechanism. Materials Chemistry and Physics, 308, 128272. https://doi.org/10.1016/j.matchemphys.2023.128272
  24. Li, X., Shen, X., Zhao, J., Yang, Y., Zhang, Q., Ding, F., Han, M., Xu, C., Yang, C., Liu, H., & Hu, Y. (2021). O3-NaFe(1/3–x)Ni1/3Mn1/3AlxO2 Cathodes with Improved Air Stability for Na-Ion Batteries. ACS Applied Materials & Interfaces, 13(28), 33015–33023. https://doi.org/10.1021/acsami.1c07554
  25. Lu, H., Sun, S., Xiao, L., Qian, J., Ai, X., Yang, H., Lu, A., & Cao, Y. (2019). High-Capacity Hard Carbon Pyrolyzed from Subbituminous Coal as Anode for Sodium-Ion Batteries. ACS Applied Energy Materials, 2(1), 729–735. https://doi.org/10.1021/acsaem.8b01784
  26. Fan, L., & Li, X. (2018). Recent advances in effective protection of sodium metal anode. Nano Energy, 53, 630–642. https://doi.org/10.1016/j.nanoen.2018.09.017

In this race to a decarbonized energy landscape, sodium-ion batteries have been pursued as a sustainable alternative to lithium-ion batteries. The abundance of the element, reduced production costs, and smaller impact on the environment compared to Li make SIBs a possible solution for large-scale energy storage. This work focuses on the current main components of SIBs, which include cathodes like layered transition metal oxides and Prussian blue analogues, and some state-of- the-art materials such as lithium-doped tunnel-type cathodes. Anodes include disodium terephthalate/multi- walled carbon nanotube composites and flash-pyrolyzed coal char that are discussed for the enhancement of their sodium storage capabilities. The performance assessment due to these different electrolytes is presented, among which are ethyl acetate-based ones and some solid-state NASICONs. Although challenges such as the low energy density and dendrite formation exist, ongoing research focuses on enhancing the lifespan, safety, and cost- effectiveness of SIBs so that broad adoption in a sustainable energy storage solution is achieved.

Keywords : Sodium-Ion Batteries (Sibs), Decarbonized Energy, Sustainable Energy Storage, Layered Transition Metal Oxides, Prussian Blue Analogues, Lithium-Doped Cathodes, Disodium Terephthalate/Multi-Walled Carbon Nanotube Composites, Flash-Pyrolyzed Coal Char, Ethyl Acetate-Based Electrolytes, Solid-State NASICON Electrolytes, Energy Density, Dendrite Formation.

Never miss an update from Papermashup

Get notified about the latest tutorials and downloads.

Subscribe by Email

Get alerts directly into your inbox after each post and stay updated.
Subscribe
OR

Subscribe by RSS

Add our RSS to your feedreader to get regular updates from us.
Subscribe