Authors :
Kavy N Panchal
Volume/Issue :
Volume 9 - 2024, Issue 10 - October
Google Scholar :
https://tinyurl.com/2fucme5y
Scribd :
https://tinyurl.com/mr2vnuph
DOI :
https://doi.org/10.5281/zenodo.14355107
Abstract :
In this race to a decarbonized energy
landscape, sodium-ion batteries have been pursued as a
sustainable alternative to lithium-ion batteries. The
abundance of the element, reduced production costs, and
smaller impact on the environment compared to Li make
SIBs a possible solution for large-scale energy storage.
This work focuses on the current main components of
SIBs, which include cathodes like layered transition metal
oxides and Prussian blue analogues, and some state-of-
the-art materials such as lithium-doped tunnel-type
cathodes. Anodes include disodium terephthalate/multi-
walled carbon nanotube composites and flash-pyrolyzed
coal char that are discussed for the enhancement of their
sodium storage capabilities. The performance assessment
due to these different electrolytes is presented, among
which are ethyl acetate-based ones and some solid-state
NASICONs. Although challenges such as the low energy
density and dendrite formation exist, ongoing research
focuses on enhancing the lifespan, safety, and cost-
effectiveness of SIBs so that broad adoption in a
sustainable energy storage solution is achieved.
Keywords :
Sodium-Ion Batteries (Sibs), Decarbonized Energy, Sustainable Energy Storage, Layered Transition Metal Oxides, Prussian Blue Analogues, Lithium-Doped Cathodes, Disodium Terephthalate/Multi-Walled Carbon Nanotube Composites, Flash-Pyrolyzed Coal Char, Ethyl Acetate-Based Electrolytes, Solid-State NASICON Electrolytes, Energy Density, Dendrite Formation.
References :
- Cao, F., Gao, G.W., Feng, Y., Getachew, B.A., & Wang, T.G. (2022). Electrochemical Properties of Metallic Coatings.
- Chang, X., Yang, Z., Liu, Y., Chen, J., Wu, M., Li, L., Chou, S., & Qiao, Y. (2024). The guarantee of large-scale energy storage: Non-flammable organic liquid electrolytes for high-safety sodium ion batteries. Energy Storage Materials, 103407. https://doi.org/10.1016/j.ensm.2024.103407
- Elisa. (2023, August 1). Sodium batteries: The technology of the future? Flash Battery. https://www.flashbattery.tech/en/sodium-batteries/
- Goikolea, E., Palomares, V., Wang, S., De Larramendi, I. R., Guo, X., Wang, G., & Rojo, T. (2020). Na‐Ion Batteries—Approaching old and new challenges. Advanced Energy Materials, 10(44). https://doi.org/10.1002/aenm.202002055
- Gupta, P., Pushpakanth, S., Haider, M. A., & Basu, S. (2022). Understanding the design of Cathode materials for Na-Ion batteries. ACS Omega, 7(7), 5605–5614. https://doi.org/10.1021/acsomega.1c05794
- Han, C., Xin, L., Wu, Z., Li, M., Long, H., & Gao, X. (2023). Preparation of disodium terephthalate/multi-walled carbon nanotube composite as an anode material for sodium-ion batteries: Performance and mechanism. Materials Chemistry and Physics, 308, 128272. https://doi.org/10.1016/j.matchemphys.2023.128272
- He, Z., Huang, Y., Liu, H., Geng, Z., Li, Y., Li, S., Deng, W., Zou, G., Hou, H., & Ji, X. (2024). Anode materials for fast charging sodium-ion batteries. Nano Energy, 109996. https://doi.org/10.1016/j.nanoen.2024.109996
- Huang, B., Cheng, L., Li, X., Zhao, Z., Yang, J., Li, Y., Pang, Y., & Cao, G. (2022). Layered Cathode Materials: Precursors, Synthesis, Microstructure, Electrochemical Properties, and Battery Performance. Small, e2107697.
- Liu, L., Xu, Q., Yin, S., Liu, Z., Li, Y., & Pang, W. (2024). Recent progress on hard carbon-based anode for sodium-ion battery. Journal of Power Sources, 615, 235116. https://doi.org/10.1016/j.jpowsour.2024.235116
- Liu, M., Xu, J., Shao, L., Shi, X., Li, C., & Sun, Z. (2024). Towards metal selenides: a promising anode for sodium-ion batteries. Chemical Communications, 60(54), 6860–6872. https://doi.org/10.1039/d4cc01974a
- Manthiram, A., Fu, Y., Chung, S.-H., & Zu, C. (2014). Challenges and opportunities for sodium-ion batteries. Chemical Reviews, 114(23), 11751-11787.
- Nguyen, T. P., & Kim, I. T. (2023). Recent advances in Sodium-Ion Batteries: Cathode materials. Materials, 16(21), 6869. https://doi.org/10.3390/ma16216869
- Palomares, E., Gonzáles-Calbet, J., Ares, J. R., & Rojo, T. (2012). Na-ion batteries: Progress and challenges. Advanced Materials, 24(41), 5446-5460.
- Ransford, C. &. (2024, June 4). Patenting sodium-ion batteries: the challenges faced as commercialisation progresses. Carpmaels & Ransford. https://www.carpmaels.com/patenting-sodium-ion-batteries-the-challenges-faced-as-commercialisation-progresses/
- Shi, W., Li, H., Zhang, D., Du, F., Zhang, Y., Wang, Z., Zhang, X., & Zhang, P. (2023). Insights into unrevealing the effects of the monovalent cation substituted tunnel-type cathode for high-performance sodium-ion batteries. Chemical Engineering Journal, 477, 146976. https://doi.org/10.1016/j.cej.2023.146976
- Thomas, J. (2024, April 3). Are sodium-ion batteries the solution for EVs? Innovation News Network. https://www.innovationnewsnetwork.com/are-sodium-ion-batteries-the-solution-for-evs/44177/
- Xu, P., Yuan, Q., Ji, W., Yu, R., Wang, F., & Huo, N. (2022). Study on the annealing phase transformation mechanism and electrochemical properties of carbon submicron fibers loaded with cobalt. Materials Express.
- Zhang, L., Xia, Y., Yang, H., Xiao, S., Zhou, J., Cao, Y., & Qian, T. (2022). The current status of sodium metal anodes for improved sodium batteries and its future perspectives. APL Materials, 10(7). https://doi.org/10.1063/5.0097264
- Synthesis of Fe-doped Mn-based Prussian blue hierarchical architecture for high-performance sodium ion batteries. (n.d.). https://ouci.dntb.gov.ua/en/works/7Prz1L1l/
- Shi, W., Li, H., Zhang, D., Du, F., Zhang, Y., Wang, Z., Zhang, X., & Zhang, P. (2023). Insights into unrevealing the effects of the monovalent cation substituted tunnel-type cathode for high-performance sodium-ion batteries. Chemical Engineering Journal, 477, 146976. https://doi.org/10.1016/j.cej.2023.146976
- Parveen, S., & Hashmi, S. (2023). Flexible gel polymer electrolyte comprising high flash point solvent adiponitrile with ethylene carbonate as co-solvent for sodium-ion batteries. Journal of Energy Storage, 67, 107519. https://doi.org/10.1016/j.est.2023.107519
- Yabuuchi, N., Kubota, K., Dahbi, M., & Komaba, S. (2014). Research development on Sodium-Ion batteries. Chemical Reviews, 114(23), 11636–11682. https://doi.org/10.1021/cr500192f
- Han, C., Xin, L., Wu, Z., Li, M., Long, H., & Gao, X. (2023). Preparation of disodium terephthalate/multi-walled carbon nanotube composite as an anode material for sodium-ion batteries: Performance and mechanism. Materials Chemistry and Physics, 308, 128272. https://doi.org/10.1016/j.matchemphys.2023.128272
- Li, X., Shen, X., Zhao, J., Yang, Y., Zhang, Q., Ding, F., Han, M., Xu, C., Yang, C., Liu, H., & Hu, Y. (2021). O3-NaFe(1/3–x)Ni1/3Mn1/3AlxO2 Cathodes with Improved Air Stability for Na-Ion Batteries. ACS Applied Materials & Interfaces, 13(28), 33015–33023. https://doi.org/10.1021/acsami.1c07554
- Lu, H., Sun, S., Xiao, L., Qian, J., Ai, X., Yang, H., Lu, A., & Cao, Y. (2019). High-Capacity Hard Carbon Pyrolyzed from Subbituminous Coal as Anode for Sodium-Ion Batteries. ACS Applied Energy Materials, 2(1), 729–735. https://doi.org/10.1021/acsaem.8b01784
- Fan, L., & Li, X. (2018). Recent advances in effective protection of sodium metal anode. Nano Energy, 53, 630–642. https://doi.org/10.1016/j.nanoen.2018.09.017
In this race to a decarbonized energy
landscape, sodium-ion batteries have been pursued as a
sustainable alternative to lithium-ion batteries. The
abundance of the element, reduced production costs, and
smaller impact on the environment compared to Li make
SIBs a possible solution for large-scale energy storage.
This work focuses on the current main components of
SIBs, which include cathodes like layered transition metal
oxides and Prussian blue analogues, and some state-of-
the-art materials such as lithium-doped tunnel-type
cathodes. Anodes include disodium terephthalate/multi-
walled carbon nanotube composites and flash-pyrolyzed
coal char that are discussed for the enhancement of their
sodium storage capabilities. The performance assessment
due to these different electrolytes is presented, among
which are ethyl acetate-based ones and some solid-state
NASICONs. Although challenges such as the low energy
density and dendrite formation exist, ongoing research
focuses on enhancing the lifespan, safety, and cost-
effectiveness of SIBs so that broad adoption in a
sustainable energy storage solution is achieved.
Keywords :
Sodium-Ion Batteries (Sibs), Decarbonized Energy, Sustainable Energy Storage, Layered Transition Metal Oxides, Prussian Blue Analogues, Lithium-Doped Cathodes, Disodium Terephthalate/Multi-Walled Carbon Nanotube Composites, Flash-Pyrolyzed Coal Char, Ethyl Acetate-Based Electrolytes, Solid-State NASICON Electrolytes, Energy Density, Dendrite Formation.