Authors :
Jyoti Kumari; Rabindra Kumar; Vijay Kumar; Sima Kumari
Volume/Issue :
Volume 11 - 2026, Issue 9 - September
Google Scholar :
https://tinyurl.com/9cvw9k9r
DOI :
https://doi.org/10.38124/ijisrt/26sep802
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Abstract :
Mixed metal oxide perovskites have emerged as an important class of functional materials because of their
outstanding structural flexibility, chemical stability, and electronics properties. The general formula of ABO3 mixed oxide
of rare-earth transition metals allows for partial or total substitution at both the A and B sites, allowing for precise control
over catalytic activity, electrical conductivity, magnetic behavior, and optical properties. The amount of accessible active
sites, adsorption capacity, and mass transport properties are all determined by the BET surface area, which is one of the
many parameters that determine their catalytic effectiveness. Particle size, pore distribution, and surface shape are all
greatly impacted by variations in synthesis processes, which ultimately alter the catalyst's surface area. This review discusses
the relationship between surface area and catalytic efficiency in mixed metal oxide perovskites, with emphasis on
photocatalytic and heterogeneous catalytic applications. The mechanisms through which surface area enhances adsorption,
charge transfer, and reaction kinetics are also examined. Furthermore, strategies for increasing surface area through nanostructuring, template-assisted synthesis, and defect engineering are summarized. The review highlights the importance of
optimizing surface characteristics to improve catalytic performance in environmental remediation and energy-related
applications.
Keywords :
Mixed Metal Oxide, Perovskite, Surface Area, Photocatalysis, Catalysis, BET Surface Area.
References :
- Kumar, R., et al. (1990). Journal of the Indian Chemical Society, 67, 508.
- Ye, X., Wang, X., et al. (2022). Dalton Transactions, 51, 1745–1753.
- R. M. N. (1986). [Doctoral dissertation, Bhagalpur University]. Bhagalpur University.
- Nicollet, C., & Tuller, H. L. (2022). Chemistry of Materials, 34, 991–997.
- Kumari, S., Kumar, B., Kumar, R., & Bhagat, S. (2004). Mixed metal oxides and catalysis. Asian Journal of Chemistry, 16(3–4), 1305–1310.
- Zeng, Z., et al. (2020). Chemical Society Reviews, 49, 1109–1143.
- Kumari, S., Kumari, B., Bishwas, B. L., & Kumar, R. (2006). Catalytic behaviour of mixed metal oxides of LnMO₄ for the thermal decomposition of carbamide. Asian Journal of Chemistry, 18(2), 1025–1031.
- Spedding, F. H., & Daane, A. H. (Eds.). (1978). The rare earths (p. 578). Iowa State University Press.
- Rao, T. S. R. P. (Ed.). (n.d.). Advances in catalysis and technology (p. 33). Wiley Eastern.
- Kumar, M., et al. (2020). Journal of Emerging Technologies and Innovative Research. 1063.
- Enger, B. C., Lodeng, R., & Holmen, A. (2009). Evaluation of reactor and catalyst performance in methane partial oxidation over modified nickel catalysts. Applied Catalysis A: General, 364(1–2), 15–26. https://doi.org/10.1016/j.apcata.2009.05.033
- Kumari, J., Kumar, R., Kumar, V., & Kumari, S. (2025). Studies on synthesis and physico-chemical properties of mixed oxide of rare earth transition metals of the type LnMO₃. Journal of Emerging Technologies and Innovative Research, 12(11), 61–68. https://doi.org/10.56975/jetir.v12i11.572396
Mixed metal oxide perovskites have emerged as an important class of functional materials because of their
outstanding structural flexibility, chemical stability, and electronics properties. The general formula of ABO3 mixed oxide
of rare-earth transition metals allows for partial or total substitution at both the A and B sites, allowing for precise control
over catalytic activity, electrical conductivity, magnetic behavior, and optical properties. The amount of accessible active
sites, adsorption capacity, and mass transport properties are all determined by the BET surface area, which is one of the
many parameters that determine their catalytic effectiveness. Particle size, pore distribution, and surface shape are all
greatly impacted by variations in synthesis processes, which ultimately alter the catalyst's surface area. This review discusses
the relationship between surface area and catalytic efficiency in mixed metal oxide perovskites, with emphasis on
photocatalytic and heterogeneous catalytic applications. The mechanisms through which surface area enhances adsorption,
charge transfer, and reaction kinetics are also examined. Furthermore, strategies for increasing surface area through nanostructuring, template-assisted synthesis, and defect engineering are summarized. The review highlights the importance of
optimizing surface characteristics to improve catalytic performance in environmental remediation and energy-related
applications.
Keywords :
Mixed Metal Oxide, Perovskite, Surface Area, Photocatalysis, Catalysis, BET Surface Area.