The Use of Nanoparticle as Absorbent in the Remediation of the Physico-Chemical Properties of Crude Oil and Waste Water Contaminated Environment


Authors : Chijioke A. Egbo; Ashaka, Godspwer O.; Abumere, Eromosele

Volume/Issue : Volume 10 - 2025, Issue 10 - October


Google Scholar : https://tinyurl.com/37d2bkee

Scribd : https://tinyurl.com/2z9mk6e8

DOI : https://doi.org/10.38124/ijisrt/25oct1350

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Abstract : In order to remove lead from an aqueous solution taken from industrial effluent and soil contaminated by crude oil, the study used snail shell nanoparticles, a plentiful and inexpensive resource. The adsorbent was described. The adsorbent was subjected to Fourier transform infrared (FTIR) examination. The morphological properties of the adsorbent were examined using a scanning electron microscope (SEM). Experimental data was optimization using Mathematica software 11.0.2.1. Temperature, contact time, and concentration were examined. Thermodynamics, kinetics, and equilibrium adsorption isotherms were examined. Langmuir, Freundlich, and isotherm models were used to assess the experimental data. Pseudo-first order, pseudo-second order, and intra-particle models were fitted to the kinetics data. The adsorption isotherm developed fits the Freundlich isotherm model well, according to the results, with the maximum correlation coefficient (R2) of 0.966. According to the thermodynamic study, the lead removal process by the snail shell nanoparticles was feasible, exothermic, and spontaneous. These findings suggest that lead can be successfully removed from aqueous solutions using snail shell nanoparticles as an adsorbent.

Keywords : Nanoparticle, Snail Shell, Lead Adsorption, Waste Water, Crude Oil Remediation.

References :

  1. C. Cojocaru, G. Zakrzewska-Trznadel, A. Jaworska, Removal of cobalt ions from aqueous solutions by polymer assisted ultrafiltration using experimental design approach. Part 1: optimization of complexation conditions, J. Hazard. Mater., 169 (2009) 599–609.
  2. A. Khan, J.L. Xing, A.M. Elseman, P.C. Gu, K. Gul, Y.J. Ai, R. Jehan, A. Alsaedi, T. Hayat, X.K. Wang, A novel magnetite nanorod-decorated Si-Schiff base complex for efficient immobilization of U(VI) and Pb (II) from water solutions, Dalton Trans., 47 (2018) 11327–11336.
  3. A. Sarı, M. Tuzen, Biosorption of cadmium (II) from aqueous solution by red algae (Ceramium virgatum): equilibrium, kinetic and thermodynamic studies, J. Hazard. Mater., 157 (2008) 448–454.
  4. Zhao, B., Zhang, J. E., Yan, W., Kang, X., Cheng, C., & Ouyang, Y. (2016). Removal of cadmium from aqueous solution using waste shells of golden apple snail. Desalination and Water Treatment57(50), 23987-24003.
  5. Oyedeko, K. F., Akinyanju, A. S., & Lasisi-Amokun, M. K. (2025). REMOVAL OF LEAD FROM TEXTILE WASTE WATER USING CHITOSAN PRODUCED FROM SNAIL SHELL. Journal of the Nigerian Society of Chemical Engineers40, 1.
  6. Ketwong, C., Trisupakitti, S., Nausri, C., & Senajuk, W. (2018). Removal of heavy metal from synthetic wastewaterusing calcined golden apple snail shells. Asian Health, Science and Technology Reports26(4), 61-70.
  7. Nwajei, B. A., Jacob, J. N., & Okuo, J. M. (2023). Comparative studies on the use of activated snail (Achanita fulica) and periwinkle shells (Typanotonus fuscatu) in the removal of heavy metal ions from aqueous solutions. Ife Journal of Science25(3), 331-343.
  8. Liu, Y., Sun, C., Xu, J., & Li, Y. (2009). The use of raw and acid-pretreated bivalve mollusk shells to remove metals from aqueous solutions. Journal of hazardous materials168(1), 156-162.
  9. Esmaeili, H., Tamjidi, S., & Abed, M. (2020). Removal of Cu (II), Co (II) and Pb (II) from synthetic and real wastewater using calcified Solamen Vaillanti snail shell. Desalination and Water Treatment174, 324-335.
  10. Sharma, A., & Devi, I. (2024). Biosorption of heavy metal ions from aqueous effluents utilising snail shell dust as a biomaterial. Environment, Development and Sustainability26(12), 31879-31896.
  11. Olanipekun, O., Aboje, A. A., & Auta, M. (2019). Optimization study on the removal of Pb (II), Cd (II) and Ni (II) from pharmaceutical wastewater using carbonized African giant snail shell (Archachatina marginata) as an adsorbent.
  12. Hossain, A., & Aditya, G. (2013). Cadmium biosorption potential of shell dust of the fresh water invasive snail Physa acuta. Journal of environmental chemical engineering1(3), 574-580.
  13. Hossain, A., Bhattacharyya, S. R., & Aditya, G. (2015). Biosorption of cadmium from aqueous solution by shell dust of the freshwater snail Lymnaea luteola. Environmental Technology & Innovation4, 82-91.
  14. Shahzad, S., Shahzad, N., Yaqub, A., Sadiq, U., Ahmad, U., & Hussain, M. (2017). Removal of heavy metal lead (Pb)(II) by biosorption process using paper shell mussel (Anodontoides ferussacianus). World J. Pharm. Med. Res.3(6), 281-288.
  15. Günay, A., Arslankaya, E., & Tosun, I. (2007). Lead removal from aqueous solution by natural and pretreated clinoptilolite: adsorption equilibrium and kinetics. Journal of hazardous materials146(1-2), 362-371.
  16. Ayawei, N., Angaye, S. S., Wankasi, D., & Dikio, E. D. (2015). Synthesis, characterization and application of Mg/Al layered double hydroxide for the degradation of congo red in aqueous solution. Open Journal of Physical Chemistry5(3), 56-70.
  17. Boparai, H. K., Joseph, M., & O’Carroll, D. M. (2011). Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles. Journal of hazardous materials186(1), 458-465.

In order to remove lead from an aqueous solution taken from industrial effluent and soil contaminated by crude oil, the study used snail shell nanoparticles, a plentiful and inexpensive resource. The adsorbent was described. The adsorbent was subjected to Fourier transform infrared (FTIR) examination. The morphological properties of the adsorbent were examined using a scanning electron microscope (SEM). Experimental data was optimization using Mathematica software 11.0.2.1. Temperature, contact time, and concentration were examined. Thermodynamics, kinetics, and equilibrium adsorption isotherms were examined. Langmuir, Freundlich, and isotherm models were used to assess the experimental data. Pseudo-first order, pseudo-second order, and intra-particle models were fitted to the kinetics data. The adsorption isotherm developed fits the Freundlich isotherm model well, according to the results, with the maximum correlation coefficient (R2) of 0.966. According to the thermodynamic study, the lead removal process by the snail shell nanoparticles was feasible, exothermic, and spontaneous. These findings suggest that lead can be successfully removed from aqueous solutions using snail shell nanoparticles as an adsorbent.

Keywords : Nanoparticle, Snail Shell, Lead Adsorption, Waste Water, Crude Oil Remediation.

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Paper Submission Last Date
31 - December - 2025

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