Authors :
Pushp Raj Harsh; Ujjwal Prasad; S. R. Kumar; K. Prasad
Volume/Issue :
Volume 11 - 2026, Issue 1 - January
Google Scholar :
https://tinyurl.com/2tkmvvfp
Scribd :
https://tinyurl.com/448bvrh4
DOI :
https://doi.org/10.38124/ijisrt/26jan1470
Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.
Abstract :
Graphene, a two-dimensional monolayer of sp2-hybridized carbon atoms arranged in a hexagonal lattice, has
emerged as one of the most extensively studied materials due to its exceptional physicochemical properties. Its unique atomic
structure gives rise to extraordinary electrical and thermal conductivity, high mechanical strength, large specific surface
area, and chemical stability, positioning graphene as a versatile platform for advanced technological applications. This
review provides a comprehensive overview of graphene, emphasizing the fundamental relationship between its structure
and distinguishing properties. Major synthesis techniques, including mechanical exfoliation, chemical vapor deposition,
liquid-phase exfoliation, chemical oxidation–reduction routes, and electrochemical exfoliation, are critically discussed with
respect to material quality, scalability, and practical feasibility. Furthermore, the review highlights recent progress in a
broad spectrum of graphene-based applications spanning electronics, sensing, energy storage and conversion, healthcare,
water purification, protective coatings, and commercialization efforts. Current challenges related to large-scale production,
defect control, and device integration are also addressed. Finally, emerging research directions and future prospects are
outlined, underscoring the potential of graphene to transition from laboratory-scale research to widespread industrial
implementation. This review aims to provide a consolidated perspective for researchers and engineers engaged in the
development of next-generation graphene-based technologies.
Keywords :
Graphene, CVD, Mechanical Exfoliation, Epitaxial Growth on Silicon Carbide, Liquid-Phase Exfoliation, rGO, Electrochemically Exfoliated Graphene.
References :
- Boehm HP, Setton R, Stumpp E (1986) Nomenclature and terminology of graphite intercalation compounds. Carbon 24:241–245
- Boehm HP, Setton R, Stumpp E (1994) Nomenclature and terminology of graphite intercalation compounds (IUPAC Recommendations 1994). Pure Appl Chem 66:1893–1901
- W. Choi et al. Synthesis of graphene and its applications: a review. 2010. 35(1): p. 52-71.
- B. Huang, et al., Preparation and characterisation of graphene. 2015. 19(sup9): p. S9-344-S9-350.
- B.J.I.J.o.I.R. Bera, A review on polymer, graphene and carbon nanotube: properties, synthesis and applications. 2017. 3(10): p. 61-70.
- Haering, R.R., 1958. Band structure of rhombohedral graphite. Can. J. Phys. 36, 352–362.
- Novoselov, K.S., Jiang, D., Schedin, F., Booth, T.J., Khotkevich, V.V., Morozov, S.V., Geim, A.K., 2005. Twodimensional atomic crystals. Proc. Natl. Acad. Sci. 102, 10451–10453.
- Geim, A.K., Novoselov, K.S., 2007. The rise of graphene. Nature Mater. 6, 183–191
- Morozov, S.V., Novoselov, K.S., Schedin, F., Jiang, D., Firsov, A.A., Geim, A.K., 2005. Twodimensional electron and hole gases at the surface of graphite. Phys. Rev. B 72, 201401.
- Partoens, B. and F. M. Peeters. 2006. From graphene to graphite: Electronic structure around the K point. Physical Review B 74 (7):075404.
- Bolotin, K. I. et al. Ultrahigh electron mobility in suspended graphene. Solid State Commun. 146, 351-355, (2008).
- Baringhaus, J. et al. Exceptional ballistic transport in epitaxial graphene nanoribbons. Nature 506, 349-354, (2014).
- Balandin, A. A. et al. Superior thermal conductivity of single-layer graphene. Nano Lett. 8, 902-907, (2008).
- Cai, W. et al. Thermal transport in suspended and supported monolayer graphene grown by chemical vapor deposition. Nano Lett. 10, 1645-1651, (2010).
- Xu, X. et al. Length-dependent thermal conductivity in suspended single-layer graphene. Nature Communications 5, (2014).
- Nair, R. et al. Fine structure constant defines visual transparency of graphene. Science 320, 1308-1308, (2008).
- Bonaccorso, F. et al. Graphene photonics and optoelectronics. Nature photonics 4, 611-622, (2010).
- Lee, C. et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene. science 321, 385-388, (2008).
- Tsoukleri, G. et al. Subjecting a Graphene Monolayer to Tension and Compression. Small 5, 2397-2402, (2009).
- Achtyl, J. L. et al. Aqueous proton transfer across single-layer graphene. Nature communications 6, (2015).
- Stoller, M. D. et al. Graphene-Based Ultracapacitors. Nano Lett. 8, 3498-3502, (2008).
- Wang, S. et al. Wettability and surface free energy of graphene films. Langmuir 25, 11078-11081, (2009).
- X. Lu, M. Yu, H. Huang, and R.S. Ruoff, Nanotechnology 10, 269. (1999).
- K.S. Novoselov, D. Jiang, F. Schedin, T.J. Booth, V.V. Khotkevich, S.V. Morozov, and A.K. Geim, Proc. Natl. Acad. Sci. 102, 10451. (2005).
- D.A. Brownson, C.E.J.P.C.C.P. Banks, Banks, The electrochemistry of CVD graphene: progress and prospects. 2012. 14(23): p. 8264-8281
- Blake, P., Hill, E. W., Castro Neto, A. H., Novoselov, K. S., Jiang, D., Yang, R., Booth, T. J. & Geim, A. K. (2007). Appl. Phys. Lett. 91, 063124
- Riedl, C., Starke, U, Bernhardt, J., Franke, M. and Heinz, K, 2007. Structural properties of the graphene SiC (0001) interface as a key for the preparation of homogeneous large-terrace graphene surfaces. Physical Review B, 76, 24540618.
- Coleman, J. N. Liquid exfoliation of defect-free graphene. Acc. Chem. Res. 46, 14-22, (2012).
- Amieva, E. J. C. et al. in Recent Advances in Graphene Research (InTech, 2016).
- Zhang, Y., et al. (2010). Electrochemical exfoliation of graphite in sulfate solution. Carbon, 48(4), 1239–1245.
- Zhang, L., Lu, Z., Zhao, Q., Huang, J., Shen, H., Zhang, Z. 2011a. Enhanced chemotherapy efficacy by sequential delivery of siRNA and anticancer drugs using PE Igrafted graphene oxide. Small 7:460–464.
- Zhang, W., Guo, Z., Huang, D., Liu, Z., Guo, X., Zhong, H. 2011b. Synergistic effect of chemo photo thermal therapy using PEGylated graphene oxide. Biomaterials 32:8555–8561.
- Johnson, J. L., Behnam, A., Pearton, S. J., and Ural, A. 2010. Hydrogen sensing using Pd functionalized multilayer graphene nanoribbon networks. Adv. Mater. 22:4877–4880.
- Cai, B., Wang, S., Huang, L., Ning, Y., Zhang, Z., and Zhang, G.J. 2014. Ultrasensitive label free detection of PNA–DNA hybridization by reduced graphene oxide field effect transistor biosensor. ACS Nano 8:2632–2638.
- Guo, C. X., H. B. Yang, Z. M. Sheng, Z. S. Lu, Q. L. Song, and C. M. Li. 2010. Layered graphene/quantum dots for photovoltaic devices. Angewandte Chemie International Edition 49:3014–3017.
- Niu, Z., L. Zhang, L. Liu, B. Zhu, H. Dong, and X. Chen. 2013. All solid state flexible ultrathin micro supercapacitors based on graphene. Advanced Materials 25:4035–4042.
- J. Abraham, et al., Tunable sieving of ions using graphene oxide membranes. 2017. 12(6): p. 546.
- M.S. Selim, S.A. El-Safty, N.A. Fatthallah, and M.A. Shenashen, Progr. Organ. Coat. 121, 160. (2018).
Graphene, a two-dimensional monolayer of sp2-hybridized carbon atoms arranged in a hexagonal lattice, has
emerged as one of the most extensively studied materials due to its exceptional physicochemical properties. Its unique atomic
structure gives rise to extraordinary electrical and thermal conductivity, high mechanical strength, large specific surface
area, and chemical stability, positioning graphene as a versatile platform for advanced technological applications. This
review provides a comprehensive overview of graphene, emphasizing the fundamental relationship between its structure
and distinguishing properties. Major synthesis techniques, including mechanical exfoliation, chemical vapor deposition,
liquid-phase exfoliation, chemical oxidation–reduction routes, and electrochemical exfoliation, are critically discussed with
respect to material quality, scalability, and practical feasibility. Furthermore, the review highlights recent progress in a
broad spectrum of graphene-based applications spanning electronics, sensing, energy storage and conversion, healthcare,
water purification, protective coatings, and commercialization efforts. Current challenges related to large-scale production,
defect control, and device integration are also addressed. Finally, emerging research directions and future prospects are
outlined, underscoring the potential of graphene to transition from laboratory-scale research to widespread industrial
implementation. This review aims to provide a consolidated perspective for researchers and engineers engaged in the
development of next-generation graphene-based technologies.
Keywords :
Graphene, CVD, Mechanical Exfoliation, Epitaxial Growth on Silicon Carbide, Liquid-Phase Exfoliation, rGO, Electrochemically Exfoliated Graphene.