Valorisation of Plastic Waste: Recycled Polyethylene Terephthalate as a Scalable Spectrally Selective Coating for Dual-Mode Solar Thermal and Radiative Cooling Applications in Tropical Buildings


Authors : Okonkwo, Boniface U.; Nwufo, Olisaemeka C.; Nwaji, Godswill N.; Okoronkwo, Chukwunenye A.; Anyanwu, Emmanuel E.

Volume/Issue : Volume 11 - 2026, Issue 2 - February


Google Scholar : https://tinyurl.com/yc55p8zv

Scribd : https://tinyurl.com/ezbyhurc

DOI : https://doi.org/10.38124/ijisrt/26feb943

Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.


Abstract : Spectrally selective surfaces are pivotal for advanced thermal systems but are often characterized by complex, energy-intensive, and costly manufacturing processes, limiting their scalability and accessibility. This work presents a sustainable and economically viable alternative by developing, fabricating, and characterisation of a low-cost spectrally selective coating derived entirely from recycled Polyethylene Terephthalate (PET) plastic waste. The coating was engineered for dual-mode operation in a hybrid solar thermal and nocturnal radiative cooling system, requiring a balance of high solar absorptance (α) and high thermal emittance (ε) in the atmospheric window (8–13 μm). The PET film was fabricated through a process of pulverizing post-consumer bottles and applying the resulting powder onto a mild steel substrate. When experimentally characterized within a full-scale hybrid system under tropical conditions, the coating demonstrated remarkable dual-functional properties: a solar absorptance of α ≈ 0.86-0.94 and a long-wave infrared emissivity of ε ≈ 0.42- 0.48. The integrated system, leveraging this coating, achieved a solar thermal efficiency of 47.11% and a nocturnal radiative cooling power of 196.86 W/m2. These results are competitive with systems using more complex commercial or engineered surfaces. This study conclusively establishes recycled PET as a viable, abundant, and effective material for spectrally selective surfaces, bridging the gap between circular waste management strategies and the pressing need for accessible renewable energy technology. The simple fabrication process offers a disruptive pathway for the scalable production of low- carbon thermal management systems, particularly in developing economies.

Keywords : Recycled PET; Spectrally Selective Coating; Circular Economy; Plastic Upcycling; Solar Absorptance; Thermal Emissivity; Hybrid Energy Systems; Sustainable Materials.

References :

  1. Granqvist, C. G. (2007). Transparent conductors as solar energy materials: A panoramic review. Solar Energy Materials and Solar Cells, 91(17), 1529-1598.
  2. Goldstein, E. A., Raman, A. P., & Fan, S. (2017). Sub-ambient non-evaporative fluid cooling with the sky. Nature Energy, 2(9), 1-8.
  3. Duffie, J. A., & Beckman, W. A. (2013). Solar engineering of thermal processes. John Wiley & Sons.
  4. Kennedy, C. E. (2002). Review of mid-to high-temperature solar selective absorber materials. National Renewable Energy Laboratory, NREL/TP-520-31267.
  5. Hossain, M. M., & Gu, M. (2016). Radiative cooling: Principles, progress, and potentials. Advanced Science, 3(7), 1500360.
  6. Zhao, D., Aili, A., Zhai, Y., Lu, J., Kidd, D., Tan, G., ... & Yin, X. (2019). Subambient cooling of water: toward real-world applications of daytime radiative cooling. Joule, 3(1), 111-123.
  7. Zhang, Q. C., & Mills, D. R. (1992). New cermet film structures with much improved selectivity for solar thermal applications. Applied Physics Letters, 60(5), 545-547.
  8. Selvakumar, N., & Barshilia, H. C. (2012). Review of physical vapor deposited (PVD) spectrally selective coatings for mid-and high-temperature solar thermal applications. Solar Energy Materials and Solar Cells, 98, 1-23.
  9. Raman, A. P., Anoma, M. A., Zhu, L., Rephaeli, E., & Fan, S. (2014). Passive radiative cooling below ambient air temperature under direct sunlight. Nature, 515(7528), 540-544.
  10. Zhai, Y., Ma, Y., David, S. N., Zhao, D., Lou, R., Tan, G.,  & Yin, X. (2017). Scalable-manufactured randomized glass-polymer hybrid metamaterial for daytime radiative cooling. Science, 355(6329), 1062-1066.
  11. Cao, F., Huang, Y., Tang, L., Sun, T., Boriskina, S. V., & Chen, G. (2016). Toward a high-efficiency regime for radiative cooling. Joule, 1(1), 1-12.
  12. IEA (2018). The Future of Cooling. International Energy Agency, Paris.
  13. Li, W., & Fan, S. (2018). Nanophotonic control of thermal radiation for energy applications [Invited]. Optics Express, 26(12), 15995-16021.
  14. Geyer, R., Jambeck, J. R., & Law, K. L. (2017). Production, use, and fate of all plastics ever made. Science Advances, 3(7), e1700782.
  15. Rahimi, A., & García, J. M. (2017). Chemical recycling of waste plastics for new materials production. Nature Reviews Chemistry, 1(6), 1-11.
  16. Stuart, B. H. (2004). Infrared spectroscopy: fundamentals and applications. John Wiley & Sons.
  17. Tabor, H. (1955). Selective radiation I. Wavelength discrimination. Transactions of the Conference on the Use of Solar Energy, 1, 24-33.
  18. Boström, T. K., Wackelgård, E., & Westin, G. (2003). Anti-reflection coatings for solution-chemically derived nickel-alumina solar absorbers. Solar Energy Materials and Solar Cells, 77(4), 405-417.
  19. Mandal, J., Fu, Y., Overvig, A. C., Jia, M., Sun, K., Shi, N. N., ... & Yang, Y. (2018). Hierarchically porous polymer coatings for highly efficient passive daytime radiative cooling. Science, 362(6412), 315-319.
  20. Vall, S., David, M., & Castell, A. (2020). The Radiative Collector-Emitter: A new concept for hybrid heating and cooling in buildings. Applied Energy, 278, 115583.
  21. Li, Y., Ji, S., Gao, Y., Luo, H., & Kanehira, M. (2013). Core-shell VO₂@ TiO₂ nanorods that combine thermochromic and photocatalytic properties for application as self-cleaning coatings. Scientific Reports, 3(1), 1-7.
  22. Eicker, U., & Dalibard, A. (2011). Photovoltaic-thermal collectors for night radiative cooling of buildings. Solar Energy, 85(7), 1322-1335.
  23. Katumba, G., Makiwa, G., Mwakikunga, B., Lu, J., & Wäckelgård, E. (2008). Optical and thermal performance of carbon nanoparticle-embedded black acrylic paints for solar collectors. Journal of Nanoscience and Nanotechnology, 8(6), 2841-2845.
  24. Kalogirou, S. A. (2004). Solar thermal collectors and applications. Progress in Energy and Combustion Science, 30(3), 231-295.
  25. Hu, M., Zhao, B., Li, J., & Wang, Y. (2015). Experimental study on a hybrid solar heating and radiative cooling system. Energy and Buildings, 106, 56-63.
  26. Rephaeli, E., Raman, A., & Fan, S. (2013). Ultrabroadband photonic structures to achieve high-performance daytime radiative cooling. Nano Letters, 13(4), 1457-1461.
  27. Zhou, L., Song, H., Liang, J., Singer, M., Zhou, M., Stegenburgs, E.,  & Chen, G. (2019). A polydimethylsiloxane-coated metal structure for all-day radiative cooling. Nature Sustainability, 2(8), 718-724.
  28. Atiganyanun, S., Plumley, J. B., Han, S. J., Hsu, K., Cytrynbaum, J., Peng, T. L., & Han, S. M. (2018). Effective radiative cooling by paint-format microsphere-based photonic random media. ACS Photonics, 5(4), 1181-1187.
  29. Gentle, A. R., & Smith, G. B. (2015). Radiative heat pumping from the Earth using surface phonon resonant nanoparticles. Nano Letters, 15(12), 8056-8061.
  30. Santamouris, M., & Feng, J. (2018). Recent progress in daytime radiative cooling: Is it the air conditioner of the future? Buildings, 8(12), 168.

Spectrally selective surfaces are pivotal for advanced thermal systems but are often characterized by complex, energy-intensive, and costly manufacturing processes, limiting their scalability and accessibility. This work presents a sustainable and economically viable alternative by developing, fabricating, and characterisation of a low-cost spectrally selective coating derived entirely from recycled Polyethylene Terephthalate (PET) plastic waste. The coating was engineered for dual-mode operation in a hybrid solar thermal and nocturnal radiative cooling system, requiring a balance of high solar absorptance (α) and high thermal emittance (ε) in the atmospheric window (8–13 μm). The PET film was fabricated through a process of pulverizing post-consumer bottles and applying the resulting powder onto a mild steel substrate. When experimentally characterized within a full-scale hybrid system under tropical conditions, the coating demonstrated remarkable dual-functional properties: a solar absorptance of α ≈ 0.86-0.94 and a long-wave infrared emissivity of ε ≈ 0.42- 0.48. The integrated system, leveraging this coating, achieved a solar thermal efficiency of 47.11% and a nocturnal radiative cooling power of 196.86 W/m2. These results are competitive with systems using more complex commercial or engineered surfaces. This study conclusively establishes recycled PET as a viable, abundant, and effective material for spectrally selective surfaces, bridging the gap between circular waste management strategies and the pressing need for accessible renewable energy technology. The simple fabrication process offers a disruptive pathway for the scalable production of low- carbon thermal management systems, particularly in developing economies.

Keywords : Recycled PET; Spectrally Selective Coating; Circular Economy; Plastic Upcycling; Solar Absorptance; Thermal Emissivity; Hybrid Energy Systems; Sustainable Materials.

Paper Submission Last Date
31 - March - 2026

SUBMIT YOUR PAPER CALL FOR PAPERS
Video Explanation for Published paper

Never miss an update from Papermashup

Get notified about the latest tutorials and downloads.

Subscribe by Email

Get alerts directly into your inbox after each post and stay updated.
Subscribe
OR

Subscribe by RSS

Add our RSS to your feedreader to get regular updates from us.
Subscribe