Authors :
Okonkwo, Boniface U.; Nwufo, Olisaemeka C.; Nwaji, Godswill N.; Okoronkwo, Chukwunenye A.; Anyanwu, Emmanuel E.
Volume/Issue :
Volume 11 - 2026, Issue 2 - February
Google Scholar :
https://tinyurl.com/yc55p8zv
Scribd :
https://tinyurl.com/ezbyhurc
DOI :
https://doi.org/10.38124/ijisrt/26feb943
Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.
Abstract :
Spectrally selective surfaces are pivotal for advanced thermal systems but are often characterized by complex,
energy-intensive, and costly manufacturing processes, limiting their scalability and accessibility. This work presents a
sustainable and economically viable alternative by developing, fabricating, and characterisation of a low-cost spectrally
selective coating derived entirely from recycled Polyethylene Terephthalate (PET) plastic waste. The coating was engineered
for dual-mode operation in a hybrid solar thermal and nocturnal radiative cooling system, requiring a balance of high solar
absorptance (α) and high thermal emittance (ε) in the atmospheric window (8–13 μm). The PET film was fabricated through
a process of pulverizing post-consumer bottles and applying the resulting powder onto a mild steel substrate. When
experimentally characterized within a full-scale hybrid system under tropical conditions, the coating demonstrated
remarkable dual-functional properties: a solar absorptance of α ≈ 0.86-0.94 and a long-wave infrared emissivity of ε ≈ 0.42-
0.48. The integrated system, leveraging this coating, achieved a solar thermal efficiency of 47.11% and a nocturnal radiative
cooling power of 196.86 W/m2. These results are competitive with systems using more complex commercial or engineered
surfaces. This study conclusively establishes recycled PET as a viable, abundant, and effective material for spectrally
selective surfaces, bridging the gap between circular waste management strategies and the pressing need for accessible
renewable energy technology. The simple fabrication process offers a disruptive pathway for the scalable production of low-
carbon thermal management systems, particularly in developing economies.
Keywords :
Recycled PET; Spectrally Selective Coating; Circular Economy; Plastic Upcycling; Solar Absorptance; Thermal Emissivity; Hybrid Energy Systems; Sustainable Materials.
References :
- Granqvist, C. G. (2007). Transparent conductors as solar energy materials: A panoramic review. Solar Energy Materials and Solar Cells, 91(17), 1529-1598.
- Goldstein, E. A., Raman, A. P., & Fan, S. (2017). Sub-ambient non-evaporative fluid cooling with the sky. Nature Energy, 2(9), 1-8.
- Duffie, J. A., & Beckman, W. A. (2013). Solar engineering of thermal processes. John Wiley & Sons.
- Kennedy, C. E. (2002). Review of mid-to high-temperature solar selective absorber materials. National Renewable Energy Laboratory, NREL/TP-520-31267.
- Hossain, M. M., & Gu, M. (2016). Radiative cooling: Principles, progress, and potentials. Advanced Science, 3(7), 1500360.
- Zhao, D., Aili, A., Zhai, Y., Lu, J., Kidd, D., Tan, G., ... & Yin, X. (2019). Subambient cooling of water: toward real-world applications of daytime radiative cooling. Joule, 3(1), 111-123.
- Zhang, Q. C., & Mills, D. R. (1992). New cermet film structures with much improved selectivity for solar thermal applications. Applied Physics Letters, 60(5), 545-547.
- Selvakumar, N., & Barshilia, H. C. (2012). Review of physical vapor deposited (PVD) spectrally selective coatings for mid-and high-temperature solar thermal applications. Solar Energy Materials and Solar Cells, 98, 1-23.
- Raman, A. P., Anoma, M. A., Zhu, L., Rephaeli, E., & Fan, S. (2014). Passive radiative cooling below ambient air temperature under direct sunlight. Nature, 515(7528), 540-544.
- Zhai, Y., Ma, Y., David, S. N., Zhao, D., Lou, R., Tan, G., & Yin, X. (2017). Scalable-manufactured randomized glass-polymer hybrid metamaterial for daytime radiative cooling. Science, 355(6329), 1062-1066.
- Cao, F., Huang, Y., Tang, L., Sun, T., Boriskina, S. V., & Chen, G. (2016). Toward a high-efficiency regime for radiative cooling. Joule, 1(1), 1-12.
- IEA (2018). The Future of Cooling. International Energy Agency, Paris.
- Li, W., & Fan, S. (2018). Nanophotonic control of thermal radiation for energy applications [Invited]. Optics Express, 26(12), 15995-16021.
- Geyer, R., Jambeck, J. R., & Law, K. L. (2017). Production, use, and fate of all plastics ever made. Science Advances, 3(7), e1700782.
- Rahimi, A., & García, J. M. (2017). Chemical recycling of waste plastics for new materials production. Nature Reviews Chemistry, 1(6), 1-11.
- Stuart, B. H. (2004). Infrared spectroscopy: fundamentals and applications. John Wiley & Sons.
- Tabor, H. (1955). Selective radiation I. Wavelength discrimination. Transactions of the Conference on the Use of Solar Energy, 1, 24-33.
- Boström, T. K., Wackelgård, E., & Westin, G. (2003). Anti-reflection coatings for solution-chemically derived nickel-alumina solar absorbers. Solar Energy Materials and Solar Cells, 77(4), 405-417.
- Mandal, J., Fu, Y., Overvig, A. C., Jia, M., Sun, K., Shi, N. N., ... & Yang, Y. (2018). Hierarchically porous polymer coatings for highly efficient passive daytime radiative cooling. Science, 362(6412), 315-319.
- Vall, S., David, M., & Castell, A. (2020). The Radiative Collector-Emitter: A new concept for hybrid heating and cooling in buildings. Applied Energy, 278, 115583.
- Li, Y., Ji, S., Gao, Y., Luo, H., & Kanehira, M. (2013). Core-shell VO₂@ TiO₂ nanorods that combine thermochromic and photocatalytic properties for application as self-cleaning coatings. Scientific Reports, 3(1), 1-7.
- Eicker, U., & Dalibard, A. (2011). Photovoltaic-thermal collectors for night radiative cooling of buildings. Solar Energy, 85(7), 1322-1335.
- Katumba, G., Makiwa, G., Mwakikunga, B., Lu, J., & Wäckelgård, E. (2008). Optical and thermal performance of carbon nanoparticle-embedded black acrylic paints for solar collectors. Journal of Nanoscience and Nanotechnology, 8(6), 2841-2845.
- Kalogirou, S. A. (2004). Solar thermal collectors and applications. Progress in Energy and Combustion Science, 30(3), 231-295.
- Hu, M., Zhao, B., Li, J., & Wang, Y. (2015). Experimental study on a hybrid solar heating and radiative cooling system. Energy and Buildings, 106, 56-63.
- Rephaeli, E., Raman, A., & Fan, S. (2013). Ultrabroadband photonic structures to achieve high-performance daytime radiative cooling. Nano Letters, 13(4), 1457-1461.
- Zhou, L., Song, H., Liang, J., Singer, M., Zhou, M., Stegenburgs, E., & Chen, G. (2019). A polydimethylsiloxane-coated metal structure for all-day radiative cooling. Nature Sustainability, 2(8), 718-724.
- Atiganyanun, S., Plumley, J. B., Han, S. J., Hsu, K., Cytrynbaum, J., Peng, T. L., & Han, S. M. (2018). Effective radiative cooling by paint-format microsphere-based photonic random media. ACS Photonics, 5(4), 1181-1187.
- Gentle, A. R., & Smith, G. B. (2015). Radiative heat pumping from the Earth using surface phonon resonant nanoparticles. Nano Letters, 15(12), 8056-8061.
- Santamouris, M., & Feng, J. (2018). Recent progress in daytime radiative cooling: Is it the air conditioner of the future? Buildings, 8(12), 168.
Spectrally selective surfaces are pivotal for advanced thermal systems but are often characterized by complex,
energy-intensive, and costly manufacturing processes, limiting their scalability and accessibility. This work presents a
sustainable and economically viable alternative by developing, fabricating, and characterisation of a low-cost spectrally
selective coating derived entirely from recycled Polyethylene Terephthalate (PET) plastic waste. The coating was engineered
for dual-mode operation in a hybrid solar thermal and nocturnal radiative cooling system, requiring a balance of high solar
absorptance (α) and high thermal emittance (ε) in the atmospheric window (8–13 μm). The PET film was fabricated through
a process of pulverizing post-consumer bottles and applying the resulting powder onto a mild steel substrate. When
experimentally characterized within a full-scale hybrid system under tropical conditions, the coating demonstrated
remarkable dual-functional properties: a solar absorptance of α ≈ 0.86-0.94 and a long-wave infrared emissivity of ε ≈ 0.42-
0.48. The integrated system, leveraging this coating, achieved a solar thermal efficiency of 47.11% and a nocturnal radiative
cooling power of 196.86 W/m2. These results are competitive with systems using more complex commercial or engineered
surfaces. This study conclusively establishes recycled PET as a viable, abundant, and effective material for spectrally
selective surfaces, bridging the gap between circular waste management strategies and the pressing need for accessible
renewable energy technology. The simple fabrication process offers a disruptive pathway for the scalable production of low-
carbon thermal management systems, particularly in developing economies.
Keywords :
Recycled PET; Spectrally Selective Coating; Circular Economy; Plastic Upcycling; Solar Absorptance; Thermal Emissivity; Hybrid Energy Systems; Sustainable Materials.